Zirconlum(IV) “Metalloazines” from Hydrazones: An “Umpolung” of a Carbonyl Group Derivative

Georgia M. Arvanitis, Jeffrey Schwartz, Donna Van Engen

Research output: Contribution to journalArticle

23 Scopus citations

Abstract

: Zr(IV) “metalloazines” have been prepared from Zr(IV) salts and hydrazone derivatives (or from Zr-(II) phosphine complexes and diazoalkanes). They are dimeric; X-ray analysis reveals an unsymmetrically bridged dizirconium center, and NMR analysis shows that the complexes are fluxional. They demonstrate susceptibility to electrophilic attack at carbon and thus represent an “umpolung” of the carbonyl group from which they were derived.

Original languageEnglish (US)
Pages (from-to)2157-2159
Number of pages3
JournalOrganometallics
Volume5
Issue number10
DOIs
StatePublished - Jan 1 1986

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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