Zinc morphology in zinc-nickel flow assisted batteries and impact on performance

Yasumasa Ito, Michael Nyce, Robert Plivelich, Martin Klein, Daniel Artemus Steingart, Sanjoy Banerjee

Research output: Contribution to journalArticle

102 Scopus citations

Abstract

The zinc morphology on repeated charging and discharging in flow-assisted zinc-nickel oxide cells was studied. The results show that higher charge rates cause more dendritic growth of zinc deposition on charging and tend to cause deterioration of battery cells. However, when the electrolyte velocity is higher than 15 cm s-1, the direction of dendrites was distorted toward the flow direction and the internal short circuit was suppressed. Good cycle life was obtained - 1500 cycles at 100% depth of discharge and C/2 charge and discharge rate. Also, the battery was scaled up to a 100 Wh prismatic cell, and more than 200 cycles were obtained.

Original languageEnglish (US)
Pages (from-to)2340-2345
Number of pages6
JournalJournal of Power Sources
Volume196
Issue number4
DOIs
StatePublished - Feb 15 2011

All Science Journal Classification (ASJC) codes

  • Electrical and Electronic Engineering
  • Energy Engineering and Power Technology
  • Renewable Energy, Sustainability and the Environment
  • Physical and Theoretical Chemistry

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    Ito, Y., Nyce, M., Plivelich, R., Klein, M., Steingart, D. A., & Banerjee, S. (2011). Zinc morphology in zinc-nickel flow assisted batteries and impact on performance. Journal of Power Sources, 196(4), 2340-2345. https://doi.org/10.1016/j.jpowsour.2010.09.065