Well-defined diblock copolymers via termination of living ROMP with anionically polymerized macromolecular aldehydes [1]

Justin M. Notestein; Li Bong W. Lee; Richard A. Register

doi:10.1021/ma012157x

Well-defined diblock copolymers via termination of living ROMP with anionically polymerized macromolecular aldehydes [1]

Justin M. Notestein, Li Bong W. Lee, Richard A. Register

Research output: Contribution to journal › Letter › peer-review

28 Scopus citations

Abstract

A method for the synthesis of diblock copolymers, by preparing ω-aldehyde-functionalized polymers anionically and employing these as macromolecular terminators for ring-opening metathesis polymerization (ROMP) was discussed. The Quirk and Kuang's method was used to prepare near-monodisperse polystyrene and polyisopropene bearing a single aldehyde functionality at the chain end. Several milliliters of degassed methanol was added with the vigorous stirring to liberate the polymeric aldehyde. The shift of the major peak to shorter elution time relative to the first block indicated successful block copolymer formation.

Original language	English (US)
Pages (from-to)	1985-1987
Number of pages	3
Journal	Macromolecules
Volume	35
Issue number	6
DOIs	https://doi.org/10.1021/ma012157x
State	Published - Mar 12 2002

All Science Journal Classification (ASJC) codes

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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title = "Well-defined diblock copolymers via termination of living ROMP with anionically polymerized macromolecular aldehydes [1]",

abstract = "A method for the synthesis of diblock copolymers, by preparing ω-aldehyde-functionalized polymers anionically and employing these as macromolecular terminators for ring-opening metathesis polymerization (ROMP) was discussed. The Quirk and Kuang's method was used to prepare near-monodisperse polystyrene and polyisopropene bearing a single aldehyde functionality at the chain end. Several milliliters of degassed methanol was added with the vigorous stirring to liberate the polymeric aldehyde. The shift of the major peak to shorter elution time relative to the first block indicated successful block copolymer formation.",

author = "Notestein, {Justin M.} and Lee, {Li Bong W.} and Register, {Richard A.}",

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T1 - Well-defined diblock copolymers via termination of living ROMP with anionically polymerized macromolecular aldehydes [1]

AU - Notestein, Justin M.

AU - Lee, Li Bong W.

AU - Register, Richard A.

PY - 2002/3/12

Y1 - 2002/3/12

N2 - A method for the synthesis of diblock copolymers, by preparing ω-aldehyde-functionalized polymers anionically and employing these as macromolecular terminators for ring-opening metathesis polymerization (ROMP) was discussed. The Quirk and Kuang's method was used to prepare near-monodisperse polystyrene and polyisopropene bearing a single aldehyde functionality at the chain end. Several milliliters of degassed methanol was added with the vigorous stirring to liberate the polymeric aldehyde. The shift of the major peak to shorter elution time relative to the first block indicated successful block copolymer formation.

AB - A method for the synthesis of diblock copolymers, by preparing ω-aldehyde-functionalized polymers anionically and employing these as macromolecular terminators for ring-opening metathesis polymerization (ROMP) was discussed. The Quirk and Kuang's method was used to prepare near-monodisperse polystyrene and polyisopropene bearing a single aldehyde functionality at the chain end. Several milliliters of degassed methanol was added with the vigorous stirring to liberate the polymeric aldehyde. The shift of the major peak to shorter elution time relative to the first block indicated successful block copolymer formation.

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DO - 10.1021/ma012157x

M3 - Letter

AN - SCOPUS:0037066215

SN - 0024-9297

VL - 35

SP - 1985

EP - 1987

JO - Macromolecules

JF - Macromolecules

IS - 6

ER -

Well-defined diblock copolymers via termination of living ROMP with anionically polymerized macromolecular aldehydes [1]

Abstract

All Science Journal Classification (ASJC) codes

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