Water soluble quantum dot nanoclusters: Energy migration in artifical materials

Megan H.J. Oh, Darcy J. Gentleman, Gregory D. Scholes

Research output: Contribution to journalArticle

12 Scopus citations

Abstract

Energy migration in self-assembled, water soluble, quantum dot (QD) nanoclusters is reported. These spherical nanoclusters are composed of CdSe QDs bound together by pepsin, a digestive enzyme found in mammals. A structural model for the clusters is suggested, based on scanning transmission electron microscopy, as well as dynamic light scattering and small angle X-ray scattering. Cluster sizes range from 100 to 400 nm in diameter and show a close-packed interior structure. Optical characterization of the absorption and emission spectra of the clusters is reported, finding photoluminescence quantum yields of up to approximately 60% in water for clusters made from core-shell CdSe-ZnS QDs. Clusters prepared from two different size populations of CdSe QD samples (3 and 4 nm in diameter) demonstrate energy migration and trapping. Resonance energy transfer (RET), from small to large dots within the QD-pepsin cluster, is observed by monitoring the quenching of the small donor dot fluorescence along with enhancement of the large acceptor dot fluorescence.

Original languageEnglish (US)
Pages (from-to)5079-5085
Number of pages7
JournalPhysical Chemistry Chemical Physics
Volume8
Issue number43
DOIs
StatePublished - Nov 13 2006
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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