V3.2W1.8O13 and studies of the V2O5WO3VO2 ternary system

R. J. Cava, D. J. Kleinman, S. M. Zahurak

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Abstract

The tungsten/vanadium ratios for the known ternary compounds in the V2O5WO3VO2 chemical system are characterized. The compounds V2.5W.5O7 and V2WO7.5 are the n = m = 3 and n = m = 4 members of a sreies of M-niobia like crystallographic shear structures. We have found the n = m = 5 member of the series at the composition V3.2W1.8O13, and report its crystallographic unit cell, powder x-ray diffraction pattern and range of temperature stability.

Original languageEnglish (US)
Pages (from-to)869-873
Number of pages5
JournalMaterials Research Bulletin
Volume18
Issue number7
DOIs
StatePublished - Jul 1983
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

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