V3.2W1.8O13 and studies of the V2O5WO3VO2 ternary system

R. J. Cava; D. J. Kleinman; S. M. Zahurak

doi:10.1016/0025-5408(83)90065-X

V_3.2W_1.8O₁₃ and studies of the V₂O₅WO₃VO₂ ternary system

R. J. Cava, D. J. Kleinman, S. M. Zahurak

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8 Scopus citations

Abstract

The tungsten/vanadium ratios for the known ternary compounds in the V₂O₅WO₃VO₂ chemical system are characterized. The compounds V_2.5W_.5O₇ and V₂WO_7.5 are the n = m = 3 and n = m = 4 members of a sreies of M-niobia like crystallographic shear structures. We have found the n = m = 5 member of the series at the composition V_3.2W_1.8O₁₃, and report its crystallographic unit cell, powder x-ray diffraction pattern and range of temperature stability.

Original language	English (US)
Pages (from-to)	869-873
Number of pages	5
Journal	Materials Research Bulletin
Volume	18
Issue number	7
DOIs	https://doi.org/10.1016/0025-5408(83)90065-X
State	Published - Jul 1983
Externally published	Yes

All Science Journal Classification (ASJC) codes

General Materials Science
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

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10.1016/0025-5408(83)90065-X

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title = "V3.2W1.8O13 and studies of the V2O5WO3VO2 ternary system",

abstract = "The tungsten/vanadium ratios for the known ternary compounds in the V2O5WO3VO2 chemical system are characterized. The compounds V2.5W.5O7 and V2WO7.5 are the n = m = 3 and n = m = 4 members of a sreies of M-niobia like crystallographic shear structures. We have found the n = m = 5 member of the series at the composition V3.2W1.8O13, and report its crystallographic unit cell, powder x-ray diffraction pattern and range of temperature stability.",

author = "Cava, {R. J.} and Kleinman, {D. J.} and Zahurak, {S. M.}",

year = "1983",

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T1 - V3.2W1.8O13 and studies of the V2O5WO3VO2 ternary system

AU - Cava, R. J.

AU - Kleinman, D. J.

AU - Zahurak, S. M.

PY - 1983/7

Y1 - 1983/7

N2 - The tungsten/vanadium ratios for the known ternary compounds in the V2O5WO3VO2 chemical system are characterized. The compounds V2.5W.5O7 and V2WO7.5 are the n = m = 3 and n = m = 4 members of a sreies of M-niobia like crystallographic shear structures. We have found the n = m = 5 member of the series at the composition V3.2W1.8O13, and report its crystallographic unit cell, powder x-ray diffraction pattern and range of temperature stability.

AB - The tungsten/vanadium ratios for the known ternary compounds in the V2O5WO3VO2 chemical system are characterized. The compounds V2.5W.5O7 and V2WO7.5 are the n = m = 3 and n = m = 4 members of a sreies of M-niobia like crystallographic shear structures. We have found the n = m = 5 member of the series at the composition V3.2W1.8O13, and report its crystallographic unit cell, powder x-ray diffraction pattern and range of temperature stability.

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V_3.2W_1.8O₁₃ and studies of the V₂O₅WO₃VO₂ ternary system

Abstract

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