Variously substituted glycals are readily prepared from glycosyl bromides using (Cp2TiCl)2

Roxanne P. Spencer; Jeffrey Schwartz

doi:10.1016/0040-4039(96)00865-9

Variously substituted glycals are readily prepared from glycosyl bromides using (Cp₂TiCl)₂

Roxanne P. Spencer
, Jeffrey Schwartz

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

Glycosyl halides, variously substituted with ether, acetal, or ester protecting groups, were converted to the corresponding glycals in high yield by reaction with (Cp₂TiCl)₂. A glycosyl chloride was less reactive than the analogous bromide.

Original language	English (US)
Pages (from-to)	4357-4360
Number of pages	4
Journal	Tetrahedron Letters
Volume	37
Issue number	25
DOIs	https://doi.org/10.1016/0040-4039(96)00865-9
State	Published - Jun 17 1996

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/0040-4039(96)00865-9

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title = "Variously substituted glycals are readily prepared from glycosyl bromides using (Cp2TiCl)2",

abstract = "Glycosyl halides, variously substituted with ether, acetal, or ester protecting groups, were converted to the corresponding glycals in high yield by reaction with (Cp2TiCl)2. A glycosyl chloride was less reactive than the analogous bromide.",

author = "Spencer, \{Roxanne P.\} and Jeffrey Schwartz",

year = "1996",

month = jun,

day = "17",

doi = "10.1016/0040-4039(96)00865-9",

language = "English (US)",

volume = "37",

pages = "4357--4360",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Ltd",

number = "25",

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TY - JOUR

T1 - Variously substituted glycals are readily prepared from glycosyl bromides using (Cp2TiCl)2

AU - Spencer, Roxanne P.

AU - Schwartz, Jeffrey

PY - 1996/6/17

Y1 - 1996/6/17

N2 - Glycosyl halides, variously substituted with ether, acetal, or ester protecting groups, were converted to the corresponding glycals in high yield by reaction with (Cp2TiCl)2. A glycosyl chloride was less reactive than the analogous bromide.

AB - Glycosyl halides, variously substituted with ether, acetal, or ester protecting groups, were converted to the corresponding glycals in high yield by reaction with (Cp2TiCl)2. A glycosyl chloride was less reactive than the analogous bromide.

UR - https://www.scopus.com/pages/publications/0029949396

UR - https://www.scopus.com/pages/publications/0029949396#tab=citedBy

U2 - 10.1016/0040-4039(96)00865-9

DO - 10.1016/0040-4039(96)00865-9

M3 - Article

AN - SCOPUS:0029949396

SN - 0040-4039

VL - 37

SP - 4357

EP - 4360

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 25

ER -

Variously substituted glycals are readily prepared from glycosyl bromides using (Cp₂TiCl)₂

Abstract

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