Abstract
The determination of the mean survival time τ (i.e., inverse reaction rate) associated with diffusion-controlled reactions among static traps is a problem of long-standing interest, dating back to the classical work of Smoluchkowski. For the broad class of model particulate- and digitized-based models considered here, we find a universal curve for the mean survival time τ for a wide range of porosities. The functional form of this universal scaling relation is motivated by rigorous bounds on τ and is expressible as a simple function of porosity, specific surface, and mean pore size.
Original language | English (US) |
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Pages (from-to) | 8814-8820 |
Number of pages | 7 |
Journal | Journal of Chemical Physics |
Volume | 106 |
Issue number | 21 |
DOIs | |
State | Published - Jun 1 1997 |
All Science Journal Classification (ASJC) codes
- General Physics and Astronomy
- Physical and Theoretical Chemistry