Ullmann Diaryl Ether Synthesis: Rate Acceleration by 2,2,6,6-Tetramethylheptane-3,5-dione

Elizabeth Buck; Zhiguo Jake Song; David Tschaen; Peter G. Dormer; R. P. Volante; Paul J. Reider

doi:10.1021/ol025839t

Ullmann Diaryl Ether Synthesis: Rate Acceleration by 2,2,6,6-Tetramethylheptane-3,5-dione

Elizabeth Buck, Zhiguo Jake Song, David Tschaen, Peter G. Dormer, R. P. Volante, Paul J. Reider

Research output: Contribution to journal › Article › peer-review

283 Scopus citations

Abstract

(matrix presented) In the copper salt catalyzed ether formation from aryl bromides or iodides and phenols, 2,2,6,6,-tetramethylheptane-3,5-dione (TMHD) was found to greatly accelerate the ordinarily difficult reaction, making it occur under more moderate temperatures and reaction times. A series catalysts. The reaction was shown to tolerate electron-rich aryl bromides and electron-neutral phenols.

Original language	English (US)
Pages (from-to)	1623-1626
Number of pages	4
Journal	Organic Letters
Volume	4
Issue number	9
DOIs	https://doi.org/10.1021/ol025839t
State	Published - May 2 2002
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol025839t

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abstract = "(matrix presented) In the copper salt catalyzed ether formation from aryl bromides or iodides and phenols, 2,2,6,6,-tetramethylheptane-3,5-dione (TMHD) was found to greatly accelerate the ordinarily difficult reaction, making it occur under more moderate temperatures and reaction times. A series catalysts. The reaction was shown to tolerate electron-rich aryl bromides and electron-neutral phenols.",

author = "Elizabeth Buck and Song, {Zhiguo Jake} and David Tschaen and Dormer, {Peter G.} and Volante, {R. P.} and Reider, {Paul J.}",

year = "2002",

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doi = "10.1021/ol025839t",

language = "English (US)",

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T1 - Ullmann Diaryl Ether Synthesis

T2 - Rate Acceleration by 2,2,6,6-Tetramethylheptane-3,5-dione

AU - Buck, Elizabeth

AU - Song, Zhiguo Jake

AU - Tschaen, David

AU - Dormer, Peter G.

AU - Volante, R. P.

AU - Reider, Paul J.

PY - 2002/5/2

Y1 - 2002/5/2

N2 - (matrix presented) In the copper salt catalyzed ether formation from aryl bromides or iodides and phenols, 2,2,6,6,-tetramethylheptane-3,5-dione (TMHD) was found to greatly accelerate the ordinarily difficult reaction, making it occur under more moderate temperatures and reaction times. A series catalysts. The reaction was shown to tolerate electron-rich aryl bromides and electron-neutral phenols.

AB - (matrix presented) In the copper salt catalyzed ether formation from aryl bromides or iodides and phenols, 2,2,6,6,-tetramethylheptane-3,5-dione (TMHD) was found to greatly accelerate the ordinarily difficult reaction, making it occur under more moderate temperatures and reaction times. A series catalysts. The reaction was shown to tolerate electron-rich aryl bromides and electron-neutral phenols.

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JO - Organic Letters

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Ullmann Diaryl Ether Synthesis: Rate Acceleration by 2,2,6,6-Tetramethylheptane-3,5-dione

Abstract

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