Tungsten complex catalyzed dehydrative decarboxylation of 2,3-dihydroxycarboxylic acids

Kyung Bae Yu Hye; Jeffrey Schwartz

doi:10.1016/S0040-4039(00)61776-8

Tungsten complex catalyzed dehydrative decarboxylation of 2,3-dihydroxycarboxylic acids

Kyung Bae Yu Hye, Jeffrey Schwartz

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

WOCl₄ catalyzes dehydrative decarboxylation of 2,3-dihydroxycarboxylic acids to enols, likely via β-lactone intermediates. Classical reagents for conversion of 3-hydroxycarboxylic acids to β-lactones fail with these substrates.

Original language	English (US)
Pages (from-to)	6787-6790
Number of pages	4
Journal	Tetrahedron Letters
Volume	33
Issue number	45
DOIs	https://doi.org/10.1016/S0040-4039(00)61776-8
State	Published - Nov 3 1992

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)61776-8

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@article{fa34369a286e441bab53e10fe458fe8a,

title = "Tungsten complex catalyzed dehydrative decarboxylation of 2,3-dihydroxycarboxylic acids",

abstract = "WOCl4 catalyzes dehydrative decarboxylation of 2,3-dihydroxycarboxylic acids to enols, likely via β-lactone intermediates. Classical reagents for conversion of 3-hydroxycarboxylic acids to β-lactones fail with these substrates.",

author = "Hye, {Kyung Bae Yu} and Jeffrey Schwartz",

year = "1992",

month = nov,

day = "3",

doi = "10.1016/S0040-4039(00)61776-8",

language = "English (US)",

volume = "33",

pages = "6787--6790",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "45",

}

TY - JOUR

T1 - Tungsten complex catalyzed dehydrative decarboxylation of 2,3-dihydroxycarboxylic acids

AU - Hye, Kyung Bae Yu

AU - Schwartz, Jeffrey

PY - 1992/11/3

Y1 - 1992/11/3

N2 - WOCl4 catalyzes dehydrative decarboxylation of 2,3-dihydroxycarboxylic acids to enols, likely via β-lactone intermediates. Classical reagents for conversion of 3-hydroxycarboxylic acids to β-lactones fail with these substrates.

AB - WOCl4 catalyzes dehydrative decarboxylation of 2,3-dihydroxycarboxylic acids to enols, likely via β-lactone intermediates. Classical reagents for conversion of 3-hydroxycarboxylic acids to β-lactones fail with these substrates.

UR - http://www.scopus.com/inward/record.url?scp=0026474868&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0026474868&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(00)61776-8

DO - 10.1016/S0040-4039(00)61776-8

M3 - Article

AN - SCOPUS:0026474868

SN - 0040-4039

VL - 33

SP - 6787

EP - 6790

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 45

ER -

Tungsten complex catalyzed dehydrative decarboxylation of 2,3-dihydroxycarboxylic acids

Abstract

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