Toward New 2D Zirconium-Based Metal-Organic Frameworks: Synthesis, Structures, and Electronic Properties

Amandine Cadiau; Lilia S. Xie; Nikita Kolobov; Aleksander Shkurenko; Muhammad Qureshi; Mohamed R. Tchalala; Sarah S. Park; Anastasiya Bavykina; Mohamed Eddaoudi; Mircea Dincǎ; Christopher H. Hendon; Jorge Gascon

doi:10.1021/acs.chemmater.9b02462

Toward New 2D Zirconium-Based Metal-Organic Frameworks: Synthesis, Structures, and Electronic Properties

Amandine Cadiau
, Lilia S. Xie
, Nikita Kolobov
, Aleksander Shkurenko
, Muhammad Qureshi
, Mohamed R. Tchalala
, Sarah S. Park
, Anastasiya Bavykina
, Mohamed Eddaoudi
, Mircea Dincǎ
, Christopher H. Hendon
, Jorge Gascon

Research output: Contribution to journal › Article › peer-review

42 Scopus citations

Abstract

Nowadays, zirconium metal-organic frameworks attract more attention because of their robustness and their easier predictability in terms of topology. Herein, we have been able to control synthetic parameters in order to construct two new 2D MOFs with the same sql topology. Both materials, ACM-10 and ACM-11, have been characterized by single-crystal X-ray diffraction, thermogravimetric analysis, and UV-vis spectroscopy. Their textural, electrochemical, and conductivity properties are presented along with the opportunities that these new topologically interesting scaffolds offer for the design of new structures.

Original language	English (US)
Pages (from-to)	97-104
Number of pages	8
Journal	Chemistry of Materials
Volume	32
Issue number	1
DOIs	https://doi.org/10.1021/acs.chemmater.9b02462
State	Published - Jan 14 2020
Externally published	Yes

All Science Journal Classification (ASJC) codes

General Chemistry
General Chemical Engineering
Materials Chemistry

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10.1021/acs.chemmater.9b02462

Cite this

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title = "Toward New 2D Zirconium-Based Metal-Organic Frameworks: Synthesis, Structures, and Electronic Properties",

abstract = "Nowadays, zirconium metal-organic frameworks attract more attention because of their robustness and their easier predictability in terms of topology. Herein, we have been able to control synthetic parameters in order to construct two new 2D MOFs with the same sql topology. Both materials, ACM-10 and ACM-11, have been characterized by single-crystal X-ray diffraction, thermogravimetric analysis, and UV-vis spectroscopy. Their textural, electrochemical, and conductivity properties are presented along with the opportunities that these new topologically interesting scaffolds offer for the design of new structures.",

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doi = "10.1021/acs.chemmater.9b02462",

language = "English (US)",

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T1 - Toward New 2D Zirconium-Based Metal-Organic Frameworks

T2 - Synthesis, Structures, and Electronic Properties

AU - Cadiau, Amandine

AU - Xie, Lilia S.

AU - Kolobov, Nikita

AU - Shkurenko, Aleksander

AU - Qureshi, Muhammad

AU - Tchalala, Mohamed R.

AU - Park, Sarah S.

AU - Bavykina, Anastasiya

AU - Eddaoudi, Mohamed

AU - Dincǎ, Mircea

AU - Hendon, Christopher H.

AU - Gascon, Jorge

PY - 2020/1/14

Y1 - 2020/1/14

N2 - Nowadays, zirconium metal-organic frameworks attract more attention because of their robustness and their easier predictability in terms of topology. Herein, we have been able to control synthetic parameters in order to construct two new 2D MOFs with the same sql topology. Both materials, ACM-10 and ACM-11, have been characterized by single-crystal X-ray diffraction, thermogravimetric analysis, and UV-vis spectroscopy. Their textural, electrochemical, and conductivity properties are presented along with the opportunities that these new topologically interesting scaffolds offer for the design of new structures.

AB - Nowadays, zirconium metal-organic frameworks attract more attention because of their robustness and their easier predictability in terms of topology. Herein, we have been able to control synthetic parameters in order to construct two new 2D MOFs with the same sql topology. Both materials, ACM-10 and ACM-11, have been characterized by single-crystal X-ray diffraction, thermogravimetric analysis, and UV-vis spectroscopy. Their textural, electrochemical, and conductivity properties are presented along with the opportunities that these new topologically interesting scaffolds offer for the design of new structures.

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JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 1

ER -

Toward New 2D Zirconium-Based Metal-Organic Frameworks: Synthesis, Structures, and Electronic Properties

Abstract

All Science Journal Classification (ASJC) codes

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