Topotactic lithium reactions with ReO3 related shear structures

D. W. Murphy; M. Greenblatt; R. J. Cava; S. M. Zahurak

doi:10.1016/0167-2738(81)90259-9

Topotactic lithium reactions with ReO₃ related shear structures

D. W. Murphy, M. Greenblatt, R. J. Cava, S. M. Zahurak

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58 Scopus citations

Abstract

Several examples of compounds with the ReO₃ structure and shear structures derived from it have been lithiated using n-BuLi. Lithiation of ReO₃ results in two new hexagonal compositions LiReO₃ and Li₂ReO₃ which are related to cubic ReO₃ by a simple twist of the structure. The extensively edge shared structured of FeV₃O₈ forms Li₂FeV₃O₈ which contains a similar amount of lithium on a per cavity basis, but cannot undergo this type of twist. Results on similar compounds are also discussed.

Original language	English (US)
Pages (from-to)	327-329
Number of pages	3
Journal	Solid State Ionics
Volume	5
Issue number	C
DOIs	https://doi.org/10.1016/0167-2738(81)90259-9
State	Published - Oct 1981
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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10.1016/0167-2738(81)90259-9

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title = "Topotactic lithium reactions with ReO3 related shear structures",

abstract = "Several examples of compounds with the ReO3 structure and shear structures derived from it have been lithiated using n-BuLi. Lithiation of ReO3 results in two new hexagonal compositions LiReO3 and Li2ReO3 which are related to cubic ReO3 by a simple twist of the structure. The extensively edge shared structured of FeV3O8 forms Li2FeV3O8 which contains a similar amount of lithium on a per cavity basis, but cannot undergo this type of twist. Results on similar compounds are also discussed.",

author = "Murphy, {D. W.} and M. Greenblatt and Cava, {R. J.} and Zahurak, {S. M.}",

year = "1981",

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doi = "10.1016/0167-2738(81)90259-9",

language = "English (US)",

volume = "5",

pages = "327--329",

journal = "Solid State Ionics",

issn = "0167-2738",

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T1 - Topotactic lithium reactions with ReO3 related shear structures

AU - Murphy, D. W.

AU - Greenblatt, M.

AU - Cava, R. J.

AU - Zahurak, S. M.

PY - 1981/10

Y1 - 1981/10

N2 - Several examples of compounds with the ReO3 structure and shear structures derived from it have been lithiated using n-BuLi. Lithiation of ReO3 results in two new hexagonal compositions LiReO3 and Li2ReO3 which are related to cubic ReO3 by a simple twist of the structure. The extensively edge shared structured of FeV3O8 forms Li2FeV3O8 which contains a similar amount of lithium on a per cavity basis, but cannot undergo this type of twist. Results on similar compounds are also discussed.

AB - Several examples of compounds with the ReO3 structure and shear structures derived from it have been lithiated using n-BuLi. Lithiation of ReO3 results in two new hexagonal compositions LiReO3 and Li2ReO3 which are related to cubic ReO3 by a simple twist of the structure. The extensively edge shared structured of FeV3O8 forms Li2FeV3O8 which contains a similar amount of lithium on a per cavity basis, but cannot undergo this type of twist. Results on similar compounds are also discussed.

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U2 - 10.1016/0167-2738(81)90259-9

DO - 10.1016/0167-2738(81)90259-9

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VL - 5

SP - 327

EP - 329

JO - Solid State Ionics

JF - Solid State Ionics

IS - C

ER -

Topotactic lithium reactions with ReO₃ related shear structures

Abstract

All Science Journal Classification (ASJC) codes

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