Topotactic lithium reactions with ReO3 related shear structures

D. W. Murphy, M. Greenblatt, Robert Joseph Cava, S. M. Zahurak

Research output: Contribution to journalArticlepeer-review

48 Scopus citations

Abstract

Several examples of compounds with the ReO3 structure and shear structures derived from it have been lithiated using n-BuLi. Lithiation of ReO3 results in two new hexagonal compositions LiReO3 and Li2ReO3 which are related to cubic ReO3 by a simple twist of the structure. The extensively edge shared structured of FeV3O8 forms Li2FeV3O8 which contains a similar amount of lithium on a per cavity basis, but cannot undergo this type of twist. Results on similar compounds are also discussed.

Original languageEnglish (US)
Pages (from-to)327-329
Number of pages3
JournalSolid State Ionics
Volume5
Issue numberC
DOIs
StatePublished - Jan 1 1981
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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