Time-reversal symmetry-breaking charge order in a kagome superconductor

The kagome lattice¹, which is the most prominent structural motif in quantum physics, benefits from inherent non-trivial geometry so that it can host diverse quantum phases, ranging from spin-liquid phases, to topological matter, to intertwined orders^2–8 and, most rarely, to unconventional superconductivity^6,9. Recently, charge sensitive probes have indicated that the kagome superconductors AV₃Sb₅ (A = K, Rb, Cs)^9–11 exhibit unconventional chiral charge order^12–19, which is analogous to the long-sought-after quantum order in the Haldane model²⁰ or Varma model²¹. However, direct evidence for the time-reversal symmetry breaking of the charge order remains elusive. Here we use muon spin relaxation to probe the kagome charge order and superconductivity in KV₃Sb₅. We observe a noticeable enhancement of the internal field width sensed by the muon ensemble, which takes place just below the charge ordering temperature and persists into the superconducting state. Notably, the muon spin relaxation rate below the charge ordering temperature is substantially enhanced by applying an external magnetic field. We further show the multigap nature of superconductivity in KV₃Sb₅ and that the Tc/λab−2 ratio (where T_c is the superconducting transition temperature and λ_ab is the magnetic penetration depth in the kagome plane) is comparable to those of unconventional high-temperature superconductors. Our results point to time-reversal symmetry-breaking charge order intertwining with unconventional superconductivity in the correlated kagome lattice.