Time-resolved HO2 detection with Faraday rotation spectroscopy in a photolysis reactor

Chu C. Teng, Chao Yan, Aric Rousso, Hongtao Zhong, Timothy Chen, Eric J. Zhang, Yiguang Ju, Gerard Wysocki

Research output: Contribution to journalArticlepeer-review

Abstract

Faraday rotation spectroscopy (FRS) employs the Faraday effect to detect Zeeman splitting in the presence of a magnetic field. In this article, we present system design and implementation of radical sensing in a photolysis reactor using FRS. High sensitivity (100 ppb) and time resolved in situ HO2 detection is enabled with a digitally balanced acquisition scheme. Specific advantages of employing FRS for sensing in such dynamic environments are examined and rigorously compared to the more established conventional laser absorption spectroscopy (LAS). Experimental results show that FRS enables HO2 detection when LAS is deficient, and FRS compares favorably in terms of precision when LAS is applicable. The immunity of FRS to spectral interferences such as absorption of hydrocarbons and other diamagnetic species absorption and optical fringing are highlighted in comparison to LAS.

Original languageEnglish (US)
Pages (from-to)2769-2779
Number of pages11
JournalOptics Express
Volume29
Issue number2
DOIs
StatePublished - Jan 18 2021

All Science Journal Classification (ASJC) codes

  • Atomic and Molecular Physics, and Optics

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