Thieno[3,2- b]thiophene-diketopyrrolopyrrole-containing polymers for high-performance organic field-effect transistors and organic photovoltaic devices

Hugo Bronstein; Zhuoying Chen; Raja Shahid Ashraf; Weimin Zhang; Junping Du; James R. Durrant; Pabitra Shakya Tuladhar; Kigook Song; Scott E. Watkins; Yves Geerts; Martijn M. Wienk; Rene A.J. Janssen; Thomas Anthopoulos; Henning Sirringhaus; Martin Heeney; Iain McCulloch

doi:10.1021/ja110619k

Thieno[3,2- b]thiophene-diketopyrrolopyrrole-containing polymers for high-performance organic field-effect transistors and organic photovoltaic devices

Hugo Bronstein
, Zhuoying Chen
, Raja Shahid Ashraf
, Weimin Zhang
, Junping Du
, James R. Durrant
, Pabitra Shakya Tuladhar
, Kigook Song
, Scott E. Watkins
, Yves Geerts
, Martijn M. Wienk
, Rene A.J. Janssen
, Thomas Anthopoulos
, Henning Sirringhaus
, Martin Heeney
, Iain McCulloch

Research output: Contribution to journal › Article › peer-review

879 Scopus citations

Abstract

We report the synthesis and polymerization of a novel thieno[3,2-b] thiophene-diketopyrrolopyrrole-based monomer. Copolymerization with thiophene afforded a polymer with a maximum hole mobility of 1.95 cm² V ^-1 s^-1, which is the highest mobility from a polymer-based OFET reported to date. Bulk-heterojunction solar cells comprising this polymer and PC₇₁BM gave a power conversion efficiency of 5.4%.

Original language	English (US)
Pages (from-to)	3272-3275
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	133
Issue number	10
DOIs	https://doi.org/10.1021/ja110619k
State	Published - Mar 16 2011
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja110619k

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Bronstein, H., Chen, Z., Ashraf, R. S., Zhang, W., Du, J., Durrant, J. R., Shakya Tuladhar, P., Song, K., Watkins, S. E., Geerts, Y., Wienk, M. M., Janssen, R. A. J., Anthopoulos, T., Sirringhaus, H., Heeney, M., & McCulloch, I. (2011). Thieno[3,2- b]thiophene-diketopyrrolopyrrole-containing polymers for high-performance organic field-effect transistors and organic photovoltaic devices. Journal of the American Chemical Society, 133(10), 3272-3275. https://doi.org/10.1021/ja110619k

@article{e110a070e3e4415f8851010817c6a58a,

title = "Thieno[3,2- b]thiophene-diketopyrrolopyrrole-containing polymers for high-performance organic field-effect transistors and organic photovoltaic devices",

abstract = "We report the synthesis and polymerization of a novel thieno[3,2-b] thiophene-diketopyrrolopyrrole-based monomer. Copolymerization with thiophene afforded a polymer with a maximum hole mobility of 1.95 cm2 V -1 s-1, which is the highest mobility from a polymer-based OFET reported to date. Bulk-heterojunction solar cells comprising this polymer and PC71BM gave a power conversion efficiency of 5.4\%.",

author = "Hugo Bronstein and Zhuoying Chen and Ashraf, \{Raja Shahid\} and Weimin Zhang and Junping Du and Durrant, \{James R.\} and \{Shakya Tuladhar\}, Pabitra and Kigook Song and Watkins, \{Scott E.\} and Yves Geerts and Wienk, \{Martijn M.\} and Janssen, \{Rene A.J.\} and Thomas Anthopoulos and Henning Sirringhaus and Martin Heeney and Iain McCulloch",

year = "2011",

month = mar,

day = "16",

doi = "10.1021/ja110619k",

language = "English (US)",

volume = "133",

pages = "3272--3275",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "10",

}

Bronstein, H, Chen, Z, Ashraf, RS, Zhang, W, Du, J, Durrant, JR, Shakya Tuladhar, P, Song, K, Watkins, SE, Geerts, Y, Wienk, MM, Janssen, RAJ, Anthopoulos, T, Sirringhaus, H, Heeney, M & McCulloch, I 2011, 'Thieno[3,2- b]thiophene-diketopyrrolopyrrole-containing polymers for high-performance organic field-effect transistors and organic photovoltaic devices', Journal of the American Chemical Society, vol. 133, no. 10, pp. 3272-3275. https://doi.org/10.1021/ja110619k

Thieno[3,2- b]thiophene-diketopyrrolopyrrole-containing polymers for high-performance organic field-effect transistors and organic photovoltaic devices. / Bronstein, Hugo; Chen, Zhuoying; Ashraf, Raja Shahid et al.
In: Journal of the American Chemical Society, Vol. 133, No. 10, 16.03.2011, p. 3272-3275.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Thieno[3,2- b]thiophene-diketopyrrolopyrrole-containing polymers for high-performance organic field-effect transistors and organic photovoltaic devices

AU - Bronstein, Hugo

AU - Chen, Zhuoying

AU - Ashraf, Raja Shahid

AU - Zhang, Weimin

AU - Du, Junping

AU - Durrant, James R.

AU - Shakya Tuladhar, Pabitra

AU - Song, Kigook

AU - Watkins, Scott E.

AU - Geerts, Yves

AU - Wienk, Martijn M.

AU - Janssen, Rene A.J.

AU - Anthopoulos, Thomas

AU - Sirringhaus, Henning

AU - Heeney, Martin

AU - McCulloch, Iain

PY - 2011/3/16

Y1 - 2011/3/16

N2 - We report the synthesis and polymerization of a novel thieno[3,2-b] thiophene-diketopyrrolopyrrole-based monomer. Copolymerization with thiophene afforded a polymer with a maximum hole mobility of 1.95 cm2 V -1 s-1, which is the highest mobility from a polymer-based OFET reported to date. Bulk-heterojunction solar cells comprising this polymer and PC71BM gave a power conversion efficiency of 5.4%.

AB - We report the synthesis and polymerization of a novel thieno[3,2-b] thiophene-diketopyrrolopyrrole-based monomer. Copolymerization with thiophene afforded a polymer with a maximum hole mobility of 1.95 cm2 V -1 s-1, which is the highest mobility from a polymer-based OFET reported to date. Bulk-heterojunction solar cells comprising this polymer and PC71BM gave a power conversion efficiency of 5.4%.

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JO - Journal of the American Chemical Society

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IS - 10

ER -

Thieno[3,2- b]thiophene-diketopyrrolopyrrole-containing polymers for high-performance organic field-effect transistors and organic photovoltaic devices

Abstract

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