TY - JOUR
T1 - Thiazepine photochemistry. the photoaddition of methanol involving participation by sulphur
AU - Semmelhack, Martin F.
AU - Kunkes, Steve
AU - Lee, Carol S.
PY - 1971/1/1
Y1 - 1971/1/1
N2 - Irradiation of 5-ethoxy-2,3-dihydro-2,2,6-trimethyl-1,4-thiazepine (1) leads to dimerization in aprotic media and solvent addition in methanol, with ring contraction via participation of sulphur; under the same conditions, the hydrochloride of (1) adds methanol without rearrangement.
AB - Irradiation of 5-ethoxy-2,3-dihydro-2,2,6-trimethyl-1,4-thiazepine (1) leads to dimerization in aprotic media and solvent addition in methanol, with ring contraction via participation of sulphur; under the same conditions, the hydrochloride of (1) adds methanol without rearrangement.
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U2 - 10.1039/C29710000698
DO - 10.1039/C29710000698
M3 - Article
AN - SCOPUS:37049124566
SN - 0577-6171
SP - 698
EP - 699
JO - Journal of the Chemical Society D: Chemical Communications
JF - Journal of the Chemical Society D: Chemical Communications
IS - 13
ER -