Thiazepine photochemistry. the photoaddition of methanol involving participation by sulphur

Martin F. Semmelhack; Steve Kunkes; Carol S. Lee

doi:10.1039/C29710000698

Thiazepine photochemistry. the photoaddition of methanol involving participation by sulphur

Martin F. Semmelhack, Steve Kunkes, Carol S. Lee

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13 Scopus citations

Abstract

Irradiation of 5-ethoxy-2,3-dihydro-2,2,6-trimethyl-1,4-thiazepine (1) leads to dimerization in aprotic media and solvent addition in methanol, with ring contraction via participation of sulphur; under the same conditions, the hydrochloride of (1) adds methanol without rearrangement.

Original language	English (US)
Pages (from-to)	698-699
Number of pages	2
Journal	Journal of the Chemical Society D: Chemical Communications
Issue number	13
DOIs	https://doi.org/10.1039/C29710000698
State	Published - Jan 1 1971
Externally published	Yes

All Science Journal Classification (ASJC) codes

Molecular Medicine

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10.1039/C29710000698

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title = "Thiazepine photochemistry. the photoaddition of methanol involving participation by sulphur",

abstract = "Irradiation of 5-ethoxy-2,3-dihydro-2,2,6-trimethyl-1,4-thiazepine (1) leads to dimerization in aprotic media and solvent addition in methanol, with ring contraction via participation of sulphur; under the same conditions, the hydrochloride of (1) adds methanol without rearrangement.",

author = "Semmelhack, {Martin F.} and Steve Kunkes and Lee, {Carol S.}",

year = "1971",

month = jan,

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doi = "10.1039/C29710000698",

language = "English (US)",

pages = "698--699",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

number = "13",

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T1 - Thiazepine photochemistry. the photoaddition of methanol involving participation by sulphur

AU - Semmelhack, Martin F.

AU - Kunkes, Steve

AU - Lee, Carol S.

PY - 1971/1/1

Y1 - 1971/1/1

N2 - Irradiation of 5-ethoxy-2,3-dihydro-2,2,6-trimethyl-1,4-thiazepine (1) leads to dimerization in aprotic media and solvent addition in methanol, with ring contraction via participation of sulphur; under the same conditions, the hydrochloride of (1) adds methanol without rearrangement.

AB - Irradiation of 5-ethoxy-2,3-dihydro-2,2,6-trimethyl-1,4-thiazepine (1) leads to dimerization in aprotic media and solvent addition in methanol, with ring contraction via participation of sulphur; under the same conditions, the hydrochloride of (1) adds methanol without rearrangement.

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DO - 10.1039/C29710000698

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EP - 699

JO - Chemical Communications

JF - Chemical Communications

IS - 13

ER -

Thiazepine photochemistry. the photoaddition of methanol involving participation by sulphur

Abstract

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