Irradiation of 5-ethoxy-2,3-dihydro-2,2,6-trimethyl-1,4-thiazepine (1) leads to dimerization in aprotic media and solvent addition in methanol, with ring contraction via participation of sulphur; under the same conditions, the hydrochloride of (1) adds methanol without rearrangement.
|Original language||English (US)|
|Number of pages||2|
|Journal||Journal of the Chemical Society D: Chemical Communications|
|State||Published - Jan 1 1971|
All Science Journal Classification (ASJC) codes
- Molecular Medicine