Abstract
An unusual, thermally reversible, 1,3-hydrogen shift occurs during irradiation of 6-benzyloxycarbonyl-amino-2,3-dihydro-1,4-thiazepines (2, 3, and the corresponding sulphoxide and sulphone of 3b); this is a special case of imine-enamine tautomerism, arising from the singlet excited state.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 988-989 |
| Number of pages | 2 |
| Journal | Journal of the Chemical Society D: Chemical Communications |
| Issue number | 16 |
| DOIs | |
| State | Published - 1971 |
| Externally published | Yes |
All Science Journal Classification (ASJC) codes
- Molecular Medicine
Fingerprint
Dive into the research topics of 'Thiazepine photochemistry. Ready 1,3-hydrogen shifts from a side-chain amide'. Together they form a unique fingerprint.Cite this
- APA
- Author
- BIBTEX
- Harvard
- Standard
- RIS
- Vancouver