An unusual, thermally reversible, 1,3-hydrogen shift occurs during irradiation of 6-benzyloxycarbonyl-amino-2,3-dihydro-1,4-thiazepines (2, 3, and the corresponding sulphoxide and sulphone of 3b); this is a special case of imine-enamine tautomerism, arising from the singlet excited state.
|Original language||English (US)|
|Number of pages||2|
|Journal||Journal of the Chemical Society D: Chemical Communications|
|State||Published - Jan 1 1971|
All Science Journal Classification (ASJC) codes
- Molecular Medicine