Thiazepine photochemistry. Ready 1,3-hydrogen shifts from a side-chain amide

M. F. Semmelhack, B. F. Gilman

Research output: Contribution to journalArticle

6 Scopus citations

Abstract

An unusual, thermally reversible, 1,3-hydrogen shift occurs during irradiation of 6-benzyloxycarbonyl-amino-2,3-dihydro-1,4-thiazepines (2, 3, and the corresponding sulphoxide and sulphone of 3b); this is a special case of imine-enamine tautomerism, arising from the singlet excited state.

Original languageEnglish (US)
Pages (from-to)988-989
Number of pages2
JournalJournal of the Chemical Society D: Chemical Communications
Issue number16
DOIs
StatePublished - Jan 1 1971
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Molecular Medicine

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