THERMODYNAMICS OF THE VOLTA EFFECT FOR SURFACE FILMS.

D. G. Hall; B. A. Pethica

doi:10.1098/rspa.1977.0076

THERMODYNAMICS OF THE VOLTA EFFECT FOR SURFACE FILMS.

D. G. Hall, B. A. Pethica

Chemical & Biological Engineering

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

An explicit thermodynamic analysis of the Volta effect for a system including adsorbed films or spread monolayers is presented in terms of surface variables. From an appropriate fundamental equation, Maxwell relations are obtained describing the effect of an applied electric field on some of the parameters characterizing surface films. An explicit discussion is made for electrolyte solutions with spread or absorbed films

Original language	English (US)
Pages (from-to)	425-439
Number of pages	15
Journal	Proc R Soc London Ser A
Volume	354
Issue number	1679
DOIs	https://doi.org/10.1098/rspa.1977.0076
State	Published - Jan 1 1977

All Science Journal Classification (ASJC) codes

Mathematics(all)
Engineering(all)
Physics and Astronomy(all)

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10.1098/rspa.1977.0076

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title = "THERMODYNAMICS OF THE VOLTA EFFECT FOR SURFACE FILMS.",

abstract = "An explicit thermodynamic analysis of the Volta effect for a system including adsorbed films or spread monolayers is presented in terms of surface variables. From an appropriate fundamental equation, Maxwell relations are obtained describing the effect of an applied electric field on some of the parameters characterizing surface films. An explicit discussion is made for electrolyte solutions with spread or absorbed films",

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