We conducted computer simulations on the phase behavior and gelation of solutions of reversibly associating polymers. The sol-gel transition, near the critical temperature for polymer-solvent phase separation, has thermodynamic signatures reminiscent of the micellization of surfactant solutions. At high temperatures, gelation is a continuous transition. Consequently, the behavior of the sol-gel transition is more complicated than previously thought.
|Original language||English (US)|
|Number of pages||4|
|Journal||Physical Review Letters|
|State||Published - Jan 1 1999|
All Science Journal Classification (ASJC) codes
- Physics and Astronomy(all)