Thermodynamic implications of confinement for a waterlike fluid

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A waterlike fluid film confined between hydrophobic plane surfaces is investigated. A method is introduced to study the films thermodynamic and phase behavior. The theory for uniform associating fluids is generalized to describe the hydrogen-bonding interactions in the fluid film.

Original languageEnglish (US)
Pages (from-to)2401-2418
Number of pages18
JournalJournal of Chemical Physics
Issue number5
StatePublished - 2001

All Science Journal Classification (ASJC) codes

  • General Physics and Astronomy
  • Physical and Theoretical Chemistry


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