The large-magnetoresistance compounds La1 − x CaxMnO3 have been studied using specific heat, sound velocity(v), and electron diffraction. For 0.63n ≤ x ≤ 0.67 charge ordering is observed at 260 K and accompanied by a dramatic (> 10%) increase in v. This simultaneous occurrence of electron and lattice ordering features implies extremely strong electron-phonon coupling, known to exist for the octahederally coordinated d4 ion and originating in the Jahn-Teller effect. A dynamic manifestation of this Jahn-Teller coupling has been suggested by Millis et al. as the origin for colossal magnetoresistance.
All Science Journal Classification (ASJC) codes
- Physics and Astronomy(all)