Thermal Cycling of a MOF-Based NO Disproportionation Catalyst

Ashley M. Wright; Chenyue Sun; Mircea Dincǎ

doi:10.1021/jacs.0c12134

Thermal Cycling of a MOF-Based NO Disproportionation Catalyst

Ashley M. Wright, Chenyue Sun, Mircea Dincǎ

Research output: Contribution to journal › Article › peer-review

44 Scopus citations

Abstract

The metal-organic framework CuI-MFU-4l reacts with NO, initially forming a copper(I)-nitrosyl at low pressure, and subsequently generates NO disproportionation products CuII-NO2 and N2O. The thermal stability of MFU-4l allows NOx to be released from the framework at temperatures greater than 200 °C. This treatment regenerates the original CuI-MFU-4l, which can engage in subsequent cycles of NO disproportionation.

Original language	English (US)
Pages (from-to)	681-686
Number of pages	6
Journal	Journal of the American Chemical Society
Volume	143
Issue number	2
DOIs	https://doi.org/10.1021/jacs.0c12134
State	Published - Jan 20 2021
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/jacs.0c12134

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abstract = "The metal-organic framework CuI-MFU-4l reacts with NO, initially forming a copper(I)-nitrosyl at low pressure, and subsequently generates NO disproportionation products CuII-NO2 and N2O. The thermal stability of MFU-4l allows NOx to be released from the framework at temperatures greater than 200 °C. This treatment regenerates the original CuI-MFU-4l, which can engage in subsequent cycles of NO disproportionation.",

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AB - The metal-organic framework CuI-MFU-4l reacts with NO, initially forming a copper(I)-nitrosyl at low pressure, and subsequently generates NO disproportionation products CuII-NO2 and N2O. The thermal stability of MFU-4l allows NOx to be released from the framework at temperatures greater than 200 °C. This treatment regenerates the original CuI-MFU-4l, which can engage in subsequent cycles of NO disproportionation.

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Thermal Cycling of a MOF-Based NO Disproportionation Catalyst

Abstract

All Science Journal Classification (ASJC) codes

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