The surface pressure of ionized monolayers

G. M. Bell; S. Levine; B. A. Pethica

doi:10.1039/tf9625800904

The surface pressure of ionized monolayers

G. M. Bell, S. Levine, B. A. Pethica

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

It is shown that the commonly accepted relation ΔΠ = ∫₀^ψo for the increase in surface pressure resulting from the charging of a monolayer is not general. The surface pressure increase also includes a term relating to the change of the " non-electrostatic " contribution to the surface free energy. An important part of this additional term originates in the fluctuation or "self-atmosphere" electrostatic potential at an ion in the monolayer and may also be described as the "discreteness-of-change" contribution. The use of two-dimensional equations of state for ionized films as a way of investigating the properties of the ionic double layer is briefly considered.

Original language	English (US)
Pages (from-to)	904-917
Number of pages	14
Journal	Transactions of the Faraday Society
Volume	58
DOIs	https://doi.org/10.1039/tf9625800904
State	Published - 1962
Externally published	Yes

All Science Journal Classification (ASJC) codes

General Engineering
General Physics and Astronomy
Physical and Theoretical Chemistry

Access to Document

10.1039/tf9625800904

Cite this

@article{a8a74fe42ed64debb9785816cc2dbb84,

title = "The surface pressure of ionized monolayers",

abstract = "It is shown that the commonly accepted relation ΔΠ = ∫0ψo for the increase in surface pressure resulting from the charging of a monolayer is not general. The surface pressure increase also includes a term relating to the change of the {"} non-electrostatic {"} contribution to the surface free energy. An important part of this additional term originates in the fluctuation or {"}self-atmosphere{"} electrostatic potential at an ion in the monolayer and may also be described as the {"}discreteness-of-change{"} contribution. The use of two-dimensional equations of state for ionized films as a way of investigating the properties of the ionic double layer is briefly considered.",

author = "Bell, \{G. M.\} and S. Levine and Pethica, \{B. A.\}",

year = "1962",

doi = "10.1039/tf9625800904",

language = "English (US)",

volume = "58",

pages = "904--917",

journal = "Transactions of the Faraday Society",

issn = "0014-7672",

publisher = "Royal Society of Chemistry",

}

TY - JOUR

T1 - The surface pressure of ionized monolayers

AU - Bell, G. M.

AU - Levine, S.

AU - Pethica, B. A.

PY - 1962

Y1 - 1962

N2 - It is shown that the commonly accepted relation ΔΠ = ∫0ψo for the increase in surface pressure resulting from the charging of a monolayer is not general. The surface pressure increase also includes a term relating to the change of the " non-electrostatic " contribution to the surface free energy. An important part of this additional term originates in the fluctuation or "self-atmosphere" electrostatic potential at an ion in the monolayer and may also be described as the "discreteness-of-change" contribution. The use of two-dimensional equations of state for ionized films as a way of investigating the properties of the ionic double layer is briefly considered.

AB - It is shown that the commonly accepted relation ΔΠ = ∫0ψo for the increase in surface pressure resulting from the charging of a monolayer is not general. The surface pressure increase also includes a term relating to the change of the " non-electrostatic " contribution to the surface free energy. An important part of this additional term originates in the fluctuation or "self-atmosphere" electrostatic potential at an ion in the monolayer and may also be described as the "discreteness-of-change" contribution. The use of two-dimensional equations of state for ionized films as a way of investigating the properties of the ionic double layer is briefly considered.

UR - https://www.scopus.com/pages/publications/33750532279

UR - https://www.scopus.com/inward/citedby.url?scp=33750532279&partnerID=8YFLogxK

U2 - 10.1039/tf9625800904

DO - 10.1039/tf9625800904

M3 - Article

AN - SCOPUS:33750532279

SN - 0014-7672

VL - 58

SP - 904

EP - 917

JO - Transactions of the Faraday Society

JF - Transactions of the Faraday Society

ER -

The surface pressure of ionized monolayers

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this