It was recently proposed that the sudden approximation should be a powerful tool for the calculation of the angular intensity distribution in high-energy atom scattering from disordered surfaces. In the present study the sudden approximation is applied to scattering from one- and two-dimensional models of: (1) Isolated adsorbed impurities on crystalline surfaces (Ar on Cu); (2) Mixed overlayers on an underlying surface (Xe+Ar mixtures on a smooth surface). The results are tested against numerically exact quantum-mechanical wave packet calculations. Except for very low collision energies, the sudden approximation gives results of excellent quantitative accuracy for both types of noncrystalline surfaces. At low energies, several features of the intensity distribution are not produced correctly by the sudden: These are found to be due mainly to double collision effects. The accuracy and validity range of the method are discussed in the light of the results obtained in the test calculations.
|Original language||English (US)|
|Number of pages||7|
|Journal||The Journal of chemical physics|
|State||Published - 1985|
All Science Journal Classification (ASJC) codes
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry