The structures of lithium inserted metal oxides: Li2FeV3O8

Robert Joseph Cava, A. Santoro, D. W. Murphy, S. Zahurak, R. S. Roth

Research output: Contribution to journalArticle

17 Scopus citations

Abstract

Neutron diffraction powder profile analysis has been used to determine the structure of Li2FeV3O8. The compound is prepared from FeV3O8, which has the VO2(B) structure type, by a lithium insertion reaction employing n-BuLi. Only minimal distortion of the host lattice occurs on Li insertion. The Li ions occupy five coordinate square pyramidal sites with an average LiO bond distance of 2.04 Å. These five coordinate sites occur commonly in the capped perovskite cavities of crystallographic shear structures based on ReO3.

Original languageEnglish (US)
Pages (from-to)309-317
Number of pages9
JournalJournal of Solid State Chemistry
Volume48
Issue number3
DOIs
StatePublished - Jul 15 1983
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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