The structures of lithium inserted metal oxides: Li2FeV3O8

Robert Joseph Cava; A. Santoro; D. W. Murphy; S. Zahurak; R. S. Roth

doi:10.1016/0022-4596(83)90087-7

The structures of lithium inserted metal oxides: Li₂FeV₃O₈

Robert Joseph Cava, A. Santoro, D. W. Murphy, S. Zahurak, R. S. Roth

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

Neutron diffraction powder profile analysis has been used to determine the structure of Li₂FeV₃O₈. The compound is prepared from FeV₃O₈, which has the VO₂(B) structure type, by a lithium insertion reaction employing n-BuLi. Only minimal distortion of the host lattice occurs on Li insertion. The Li ions occupy five coordinate square pyramidal sites with an average LiO bond distance of 2.04 Å. These five coordinate sites occur commonly in the capped perovskite cavities of crystallographic shear structures based on ReO₃.

Original language	English (US)
Pages (from-to)	309-317
Number of pages	9
Journal	Journal of Solid State Chemistry
Volume	48
Issue number	3
DOIs	https://doi.org/10.1016/0022-4596(83)90087-7
State	Published - Jul 15 1983
Externally published	Yes

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/0022-4596(83)90087-7

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title = "The structures of lithium inserted metal oxides: Li2FeV3O8",

abstract = "Neutron diffraction powder profile analysis has been used to determine the structure of Li2FeV3O8. The compound is prepared from FeV3O8, which has the VO2(B) structure type, by a lithium insertion reaction employing n-BuLi. Only minimal distortion of the host lattice occurs on Li insertion. The Li ions occupy five coordinate square pyramidal sites with an average LiO bond distance of 2.04 {\AA}. These five coordinate sites occur commonly in the capped perovskite cavities of crystallographic shear structures based on ReO3.",

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AU - Cava, Robert Joseph

AU - Santoro, A.

AU - Murphy, D. W.

AU - Zahurak, S.

AU - Roth, R. S.

PY - 1983/7/15

Y1 - 1983/7/15

N2 - Neutron diffraction powder profile analysis has been used to determine the structure of Li2FeV3O8. The compound is prepared from FeV3O8, which has the VO2(B) structure type, by a lithium insertion reaction employing n-BuLi. Only minimal distortion of the host lattice occurs on Li insertion. The Li ions occupy five coordinate square pyramidal sites with an average LiO bond distance of 2.04 Å. These five coordinate sites occur commonly in the capped perovskite cavities of crystallographic shear structures based on ReO3.

AB - Neutron diffraction powder profile analysis has been used to determine the structure of Li2FeV3O8. The compound is prepared from FeV3O8, which has the VO2(B) structure type, by a lithium insertion reaction employing n-BuLi. Only minimal distortion of the host lattice occurs on Li insertion. The Li ions occupy five coordinate square pyramidal sites with an average LiO bond distance of 2.04 Å. These five coordinate sites occur commonly in the capped perovskite cavities of crystallographic shear structures based on ReO3.

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The structures of lithium inserted metal oxides: Li₂FeV₃O₈

Abstract

All Science Journal Classification (ASJC) codes

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