The structures of lithium-inserted metal oxides: LiReO3 and Li2ReO3

R. J. Cava; A. Santoro; D. W. Murphy; S. Zahurak; R. S. Roth

doi:10.1016/0022-4596(82)90004-4

The structures of lithium-inserted metal oxides: LiReO₃ and Li₂ReO₃

R. J. Cava, A. Santoro, D. W. Murphy, S. Zahurak, R. S. Roth

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Abstract

The crystal structures of LiReO₃ and Li₂ReO₃, obtained by Li insertion into ReO₃, were determined by neutron diffraction powder profile analysis. For both phases, the ReO₃ host lattice, made exclusively of corner-shared octahedra, was altered significantly on Li insertion without breaking bonds. The original 12-coordinated perovskite-like cavity was changed into two octahedral sites, which are occupied by the lithium ions.

Original language	English (US)
Pages (from-to)	251-262
Number of pages	12
Journal	Journal of Solid State Chemistry
Volume	42
Issue number	3
DOIs	https://doi.org/10.1016/0022-4596(82)90004-4
State	Published - May 1982
Externally published	Yes

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/0022-4596(82)90004-4

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abstract = "The crystal structures of LiReO3 and Li2ReO3, obtained by Li insertion into ReO3, were determined by neutron diffraction powder profile analysis. For both phases, the ReO3 host lattice, made exclusively of corner-shared octahedra, was altered significantly on Li insertion without breaking bonds. The original 12-coordinated perovskite-like cavity was changed into two octahedral sites, which are occupied by the lithium ions.",

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AU - Zahurak, S.

AU - Roth, R. S.

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AB - The crystal structures of LiReO3 and Li2ReO3, obtained by Li insertion into ReO3, were determined by neutron diffraction powder profile analysis. For both phases, the ReO3 host lattice, made exclusively of corner-shared octahedra, was altered significantly on Li insertion without breaking bonds. The original 12-coordinated perovskite-like cavity was changed into two octahedral sites, which are occupied by the lithium ions.

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The structures of lithium-inserted metal oxides: LiReO₃ and Li₂ReO₃

Abstract

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