TY - JOUR
T1 - The structural analysis of phase space trajectories
AU - Luo, Zi Ping
AU - Chang, Britton
AU - Rabitz, Herschel
N1 - Funding Information:
The authors acknowledge support from the Department of Energy for this research.
PY - 1986/6/1
Y1 - 1986/6/1
N2 - Multidimensional phase space trajectories can be difficult to understand due to their complexity and the typically high dimensionality of the space. This paper proposes a global perspective to the problem having two aspects: first, the trajectory is viewed geometrically and analyzed structurally and second, the detailed trajectory information is compacted into a small number of averaged but global quantities. Several basic structural parameters such as the center of mass, principal moments of inertia, eigenvalues and eigenvectors of the momenta ellipsoid, average speed, etc. are defined to characterize trajectories. Additionally, the sensitivity coefficients of these newly defined quantities are examined. As illustrative examples, the Lotka oscillator and the H2O2 oxidation system are discussed. Finally, some interesting asymptotic properties of oscillatory systems are presented as a result of this work.
AB - Multidimensional phase space trajectories can be difficult to understand due to their complexity and the typically high dimensionality of the space. This paper proposes a global perspective to the problem having two aspects: first, the trajectory is viewed geometrically and analyzed structurally and second, the detailed trajectory information is compacted into a small number of averaged but global quantities. Several basic structural parameters such as the center of mass, principal moments of inertia, eigenvalues and eigenvectors of the momenta ellipsoid, average speed, etc. are defined to characterize trajectories. Additionally, the sensitivity coefficients of these newly defined quantities are examined. As illustrative examples, the Lotka oscillator and the H2O2 oxidation system are discussed. Finally, some interesting asymptotic properties of oscillatory systems are presented as a result of this work.
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U2 - 10.1016/0301-0104(86)80054-4
DO - 10.1016/0301-0104(86)80054-4
M3 - Article
AN - SCOPUS:46149133438
SN - 0301-0104
VL - 105
SP - 41
EP - 50
JO - Chemical Physics
JF - Chemical Physics
IS - 1-2
ER -