The role of transition metal oxides in chargegeneration layers for stacked organic light-emitting diodes

Sami Hamwi, Jens Meyer, Michael Kröger, Thomas Winkler, Marco Witte, Thomas Riedl, Antoine Kahn, Wolfgang Kowalsky

Research output: Contribution to journalArticlepeer-review

151 Scopus citations


The mechanism of charge generation in transition metal oxide (TMO)-based charge-generation layers (CGL) used in stacked organic light-emitting diodes (OLEDs) is reported upon. An interconnecting unit between two vertically stacked OLEDs, consisting of an abrupt heterointerface between a Cs2CO 3doped 4,7-diphenyl-1,10-phenanthroline layer and a WO3 film is investigated. Minimum thicknesses are determined for these layers to allow for simultaneous operation of both sub-OLEDs in the stacked device. Luminance - current density - voltage measurements, angular dependent spectral emission characteristics, and optical device simulations lead to minimum thicknesses of the n-type doped layer and the TMO layer of 5 and 2.5 nm, respectively. Using data on interface energetic determined by ultraviolet photoelectron and inverse photoemission spectroscopy, it is shown that the actual charge generation occurs between the WO3 layer and its neighboring hole-transport material, 4, 4', 4'-tris(N-carbazolyl)-triphenyl amine. The role of the adjacent n-type doped electron transport layer is only to facilitate electron injection from the TMO into the adjacent sub-OLED.

Original languageEnglish (US)
Pages (from-to)1762-1766
Number of pages5
JournalAdvanced Functional Materials
Issue number11
StatePublished - Jun 9 2010

All Science Journal Classification (ASJC) codes

  • General Chemistry
  • General Materials Science
  • Condensed Matter Physics


Dive into the research topics of 'The role of transition metal oxides in chargegeneration layers for stacked organic light-emitting diodes'. Together they form a unique fingerprint.

Cite this