The properties of ionized monolayers: Part 2. - The thermodynamics of the ionic double layer of sodium dodecyl sulphate

E. Matijević, B. A. Pethica

Research output: Contribution to journalArticlepeer-review

11 Scopus citations

Abstract

The heats of adsorption of sodium dodecyl sulphate at the air/water interface are calculated from the experimental data of part 1.6 These heats of adsorption are compared with the heats calculated from the free energies of formation of the double layer on the model of Derjaguin, Verwey and Overbeek. The serious discrepancies between measured and calculated heats are discussed in terms of ion-pair formation at the interface, and changes in energy of solvation of ions near a dielectric interface.

Original languageEnglish (US)
Pages (from-to)1390-1399
Number of pages10
JournalTransactions of the Faraday Society
Volume54
DOIs
StatePublished - Jan 1 1958
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Engineering(all)
  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Fingerprint Dive into the research topics of 'The properties of ionized monolayers: Part 2. - The thermodynamics of the ionic double layer of sodium dodecyl sulphate'. Together they form a unique fingerprint.

Cite this