The Preparation of Alkenyl Fluorides from Organometallic Reagents

Seung Han Lee, Martin Riediker, Jeffrey Schwartz

Research output: Contribution to journalArticle

4 Scopus citations

Abstract

Fluorination of alkenyllithium reagents can be accomplished in acceptable yield under conditions which give rise to low competitive alkene formation. These reactions are abetted by the use of the low temperature soluble, mild fluorinating agent N-fluoro-N-tert-butylbenzenesulfonamide; "simpler" fluorinating reagents such as F2, XeF2 or FCIO3 failed to give acceptable amounts of the fluoroolefin with these alkenyllithiums.

Original languageEnglish (US)
Pages (from-to)760-766
Number of pages7
JournalBulletin of the Korean Chemical Society
Volume19
Issue number7
StatePublished - Jul 20 1998

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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