The Preparation of Alkenyl Fluorides from Organometallic Reagents

Seung Han Lee; Martin Riediker; Jeffrey Schwartz

The Preparation of Alkenyl Fluorides from Organometallic Reagents

Seung Han Lee, Martin Riediker, Jeffrey Schwartz

Research output: Contribution to journal › Article › peer-review

Abstract

Fluorination of alkenyllithium reagents can be accomplished in acceptable yield under conditions which give rise to low competitive alkene formation. These reactions are abetted by the use of the low temperature soluble, mild fluorinating agent N-fluoro-N-tert-butylbenzenesulfonamide; "simpler" fluorinating reagents such as F₂, XeF₂ or FCIO₃ failed to give acceptable amounts of the fluoroolefin with these alkenyllithiums.

Original language	English (US)
Pages (from-to)	760-766
Number of pages	7
Journal	Bulletin of the Korean Chemical Society
Volume	19
Issue number	7
State	Published - Jul 20 1998

All Science Journal Classification (ASJC) codes

General Chemistry

Cite this

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abstract = "Fluorination of alkenyllithium reagents can be accomplished in acceptable yield under conditions which give rise to low competitive alkene formation. These reactions are abetted by the use of the low temperature soluble, mild fluorinating agent N-fluoro-N-tert-butylbenzenesulfonamide; {"}simpler{"} fluorinating reagents such as F2, XeF2 or FCIO3 failed to give acceptable amounts of the fluoroolefin with these alkenyllithiums.",

author = "Lee, {Seung Han} and Martin Riediker and Jeffrey Schwartz",

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AU - Lee, Seung Han

AU - Riediker, Martin

AU - Schwartz, Jeffrey

PY - 1998/7/20

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N2 - Fluorination of alkenyllithium reagents can be accomplished in acceptable yield under conditions which give rise to low competitive alkene formation. These reactions are abetted by the use of the low temperature soluble, mild fluorinating agent N-fluoro-N-tert-butylbenzenesulfonamide; "simpler" fluorinating reagents such as F2, XeF2 or FCIO3 failed to give acceptable amounts of the fluoroolefin with these alkenyllithiums.

AB - Fluorination of alkenyllithium reagents can be accomplished in acceptable yield under conditions which give rise to low competitive alkene formation. These reactions are abetted by the use of the low temperature soluble, mild fluorinating agent N-fluoro-N-tert-butylbenzenesulfonamide; "simpler" fluorinating reagents such as F2, XeF2 or FCIO3 failed to give acceptable amounts of the fluoroolefin with these alkenyllithiums.

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AN - SCOPUS:0032392765

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ER -

The Preparation of Alkenyl Fluorides from Organometallic Reagents

Abstract

All Science Journal Classification (ASJC) codes

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