The preparation of a di(cyclopentadienyl)zirconium methylene species from a phosphorane

Jeffrey Schwartz; Kerrie I. Gell

doi:10.1016/S0022-328X(00)94370-5

The preparation of a di(cyclopentadienyl)zirconium methylene species from a phosphorane

Jeffrey Schwartz, Kerrie I. Gell

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Abstract

Cp₂Zr(PPh₂Me)₂ reacts with CH₂=PPh₃ to give Cp₂Zr(=CH₂)(PPh₂Me), the first example of a Group IV metal carbene complex.

Original language	English (US)
Pages (from-to)	C1-C2
Journal	Journal of Organometallic Chemistry
Volume	184
Issue number	1
DOIs	https://doi.org/10.1016/S0022-328X(00)94370-5
State	Published - Jan 8 1980

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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title = "The preparation of a di(cyclopentadienyl)zirconium methylene species from a phosphorane",

abstract = "Cp2Zr(PPh2Me)2 reacts with CH2=PPh3 to give Cp2Zr(=CH2)(PPh2Me), the first example of a Group IV metal carbene complex.",

author = "Jeffrey Schwartz and Gell, {Kerrie I.}",

year = "1980",

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AU - Gell, Kerrie I.

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AB - Cp2Zr(PPh2Me)2 reacts with CH2=PPh3 to give Cp2Zr(=CH2)(PPh2Me), the first example of a Group IV metal carbene complex.

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The preparation of a di(cyclopentadienyl)zirconium methylene species from a phosphorane

Abstract

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