The oxidation of C4 molecules on vanadyl pyrophosphate catalysts

V. V. Guliants; Jay Burton Benziger; Sankaran Sundaresan

doi:10.1016/s0167-2991(96)80310-7

The oxidation of C₄ molecules on vanadyl pyrophosphate catalysts

V. V. Guliants, Jay Burton Benziger, Sankaran Sundaresan

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Vanadyl pyrophosphate catalysts displayed a variety of catalytic functionalities in the oxidation of C₄ molecules. Hydrocarbons were isomerized and dehydrogenated to olefins, as well as being oxidized. Branched hydrocarbons did not desorb from the pyrophosphate catalyst surface and appeared to undergo total oxidation. Alcohols were dehydrated to olefins and also were isomerized. 1,4 Butanediol was oxidized to maleic anhydride with very high selectivity. An active site for the initial CH bond activation at a cis-(su)peroxo oxovanadium(V) dimer site is proposed.

Original language	English (US)
Pages (from-to)	991-1000
Number of pages	10
Journal	Studies in Surface Science and Catalysis
Volume	101 B
DOIs	https://doi.org/10.1016/s0167-2991(96)80310-7
State	Published - 1996

All Science Journal Classification (ASJC) codes

Catalysis
Condensed Matter Physics
Physical and Theoretical Chemistry
Surfaces, Coatings and Films
Materials Chemistry

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@article{13a79fb3cac242049b2ae3b87ba5be1a,

title = "The oxidation of C4 molecules on vanadyl pyrophosphate catalysts",

abstract = "Vanadyl pyrophosphate catalysts displayed a variety of catalytic functionalities in the oxidation of C4 molecules. Hydrocarbons were isomerized and dehydrogenated to olefins, as well as being oxidized. Branched hydrocarbons did not desorb from the pyrophosphate catalyst surface and appeared to undergo total oxidation. Alcohols were dehydrated to olefins and also were isomerized. 1,4 Butanediol was oxidized to maleic anhydride with very high selectivity. An active site for the initial CH bond activation at a cis-(su)peroxo oxovanadium(V) dimer site is proposed.",

author = "Guliants, {V. V.} and Benziger, {Jay Burton} and Sankaran Sundaresan",

note = "Funding Information: This work was supported by the Amoco Chemical Corporation and the National Science Foundation Grant CTS-9100BO.",

year = "1996",

doi = "10.1016/s0167-2991(96)80310-7",

language = "English (US)",

volume = "101 B",

pages = "991--1000",

journal = "Studies in Surface Science and Catalysis",

issn = "0167-2991",

publisher = "Elsevier BV",

}

TY - JOUR

T1 - The oxidation of C4 molecules on vanadyl pyrophosphate catalysts

AU - Guliants, V. V.

AU - Benziger, Jay Burton

AU - Sundaresan, Sankaran

N1 - Funding Information: This work was supported by the Amoco Chemical Corporation and the National Science Foundation Grant CTS-9100BO.

PY - 1996

Y1 - 1996

N2 - Vanadyl pyrophosphate catalysts displayed a variety of catalytic functionalities in the oxidation of C4 molecules. Hydrocarbons were isomerized and dehydrogenated to olefins, as well as being oxidized. Branched hydrocarbons did not desorb from the pyrophosphate catalyst surface and appeared to undergo total oxidation. Alcohols were dehydrated to olefins and also were isomerized. 1,4 Butanediol was oxidized to maleic anhydride with very high selectivity. An active site for the initial CH bond activation at a cis-(su)peroxo oxovanadium(V) dimer site is proposed.

AB - Vanadyl pyrophosphate catalysts displayed a variety of catalytic functionalities in the oxidation of C4 molecules. Hydrocarbons were isomerized and dehydrogenated to olefins, as well as being oxidized. Branched hydrocarbons did not desorb from the pyrophosphate catalyst surface and appeared to undergo total oxidation. Alcohols were dehydrated to olefins and also were isomerized. 1,4 Butanediol was oxidized to maleic anhydride with very high selectivity. An active site for the initial CH bond activation at a cis-(su)peroxo oxovanadium(V) dimer site is proposed.

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U2 - 10.1016/s0167-2991(96)80310-7

DO - 10.1016/s0167-2991(96)80310-7

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VL - 101 B

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EP - 1000

JO - Studies in Surface Science and Catalysis

JF - Studies in Surface Science and Catalysis

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