The nature of the phase transitions in fluid mercury

Leonid A. Turkevich; Morrel H. Cohen

doi:10.1016/0022-3093(84)90523-4

The nature of the phase transitions in fluid mercury

Leonid A. Turkevich
, Morrel H. Cohen

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

We review the metal-nonmetal transition in expanded liquid mercury and the dielectric transition in dense mercury vapor. Previous explanations for these transitions are found to be deficient. We propose that the high-temperature, high-pressure fluid is an excitonic insulator phase. The phase diagram for the excitonic insulator naturally explains both the metal-non-metal and the dielectric transitions.

Original language	English (US)
Pages (from-to)	13-22
Number of pages	10
Journal	Journal of Non-Crystalline Solids
Volume	61-62
Issue number	PART 1
DOIs	https://doi.org/10.1016/0022-3093(84)90523-4
State	Published - Jan 1984
Externally published	Yes

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Materials Chemistry

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10.1016/0022-3093(84)90523-4

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title = "The nature of the phase transitions in fluid mercury",

abstract = "We review the metal-nonmetal transition in expanded liquid mercury and the dielectric transition in dense mercury vapor. Previous explanations for these transitions are found to be deficient. We propose that the high-temperature, high-pressure fluid is an excitonic insulator phase. The phase diagram for the excitonic insulator naturally explains both the metal-non-metal and the dielectric transitions.",

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year = "1984",

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AU - Turkevich, Leonid A.

AU - Cohen, Morrel H.

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N2 - We review the metal-nonmetal transition in expanded liquid mercury and the dielectric transition in dense mercury vapor. Previous explanations for these transitions are found to be deficient. We propose that the high-temperature, high-pressure fluid is an excitonic insulator phase. The phase diagram for the excitonic insulator naturally explains both the metal-non-metal and the dielectric transitions.

AB - We review the metal-nonmetal transition in expanded liquid mercury and the dielectric transition in dense mercury vapor. Previous explanations for these transitions are found to be deficient. We propose that the high-temperature, high-pressure fluid is an excitonic insulator phase. The phase diagram for the excitonic insulator naturally explains both the metal-non-metal and the dielectric transitions.

UR - https://www.scopus.com/pages/publications/0020495833

UR - https://www.scopus.com/pages/publications/0020495833#tab=citedBy

U2 - 10.1016/0022-3093(84)90523-4

DO - 10.1016/0022-3093(84)90523-4

M3 - Article

AN - SCOPUS:0020495833

SN - 0022-3093

VL - 61-62

SP - 13

EP - 22

JO - Journal of Non-Crystalline Solids

JF - Journal of Non-Crystalline Solids

IS - PART 1

ER -

The nature of the phase transitions in fluid mercury

Abstract

All Science Journal Classification (ASJC) codes

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