The Mechanism of Titanium Complex-Catalyzed Reduction of Aryl Halides by Sodium Borohydride Is Strongly Solvent Dependent

Yumin Liu; Jeffrey Schwartz

doi:10.1021/jo00084a003

The Mechanism of Titanium Complex-Catalyzed Reduction of Aryl Halides by Sodium Borohydride Is Strongly Solvent Dependent

Yumin Liu, Jeffrey Schwartz

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

The titanium complex-catalyzed reduction of aryl halides by sodium borohydride in dimethylacetamide (DMA) or ethers proceeds by electron transfer from a reduced titanium species, yielding an intermediate aryl radical.

Original language	English (US)
Pages (from-to)	940-942
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	59
Issue number	5
DOIs	https://doi.org/10.1021/jo00084a003
State	Published - Mar 1 1994

All Science Journal Classification (ASJC) codes

Organic Chemistry

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@article{ee27cb721f8f4347a9021ba54f7b7e8d,

title = "The Mechanism of Titanium Complex-Catalyzed Reduction of Aryl Halides by Sodium Borohydride Is Strongly Solvent Dependent",

abstract = "The titanium complex-catalyzed reduction of aryl halides by sodium borohydride in dimethylacetamide (DMA) or ethers proceeds by electron transfer from a reduced titanium species, yielding an intermediate aryl radical.",

author = "Yumin Liu and Jeffrey Schwartz",

year = "1994",

month = mar,

day = "1",

doi = "10.1021/jo00084a003",

language = "English (US)",

volume = "59",

pages = "940--942",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

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T1 - The Mechanism of Titanium Complex-Catalyzed Reduction of Aryl Halides by Sodium Borohydride Is Strongly Solvent Dependent

AU - Liu, Yumin

AU - Schwartz, Jeffrey

PY - 1994/3/1

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N2 - The titanium complex-catalyzed reduction of aryl halides by sodium borohydride in dimethylacetamide (DMA) or ethers proceeds by electron transfer from a reduced titanium species, yielding an intermediate aryl radical.

AB - The titanium complex-catalyzed reduction of aryl halides by sodium borohydride in dimethylacetamide (DMA) or ethers proceeds by electron transfer from a reduced titanium species, yielding an intermediate aryl radical.

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U2 - 10.1021/jo00084a003

DO - 10.1021/jo00084a003

M3 - Article

AN - SCOPUS:0001271509

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SP - 940

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JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 5

ER -

The Mechanism of Titanium Complex-Catalyzed Reduction of Aryl Halides by Sodium Borohydride Is Strongly Solvent Dependent

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