The mechanism of β-hydride elimination from transition metal alkyls (d8): Kinetic deuterium isotope effect

John Evans; Jeffrey Schwartz; Peter W. Urquhart

doi:10.1016/S0022-328X(00)88213-3

The mechanism of β-hydride elimination from transition metal alkyls (d⁸): Kinetic deuterium isotope effect

John Evans
, Jeffrey Schwartz
, Peter W. Urquhart

Research output: Contribution to journal › Article › peer-review

80 Scopus citations

Abstract

The kinetic isotope effect for β-hydride elimination from alkyliridium(I) complexes has bee found to be k_H/k_D = 2.28 ± 0.20.

Original language	English (US)
Pages (from-to)	C37-C39
Journal	Journal of Organometallic Chemistry
Volume	81
Issue number	3
DOIs	https://doi.org/10.1016/S0022-328X(00)88213-3
State	Published - Nov 26 1974

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S0022-328X(00)88213-3

Cite this

@article{bae349688ff0475ea672c719b8792e1f,

title = "The mechanism of β-hydride elimination from transition metal alkyls (d8): Kinetic deuterium isotope effect",

abstract = "The kinetic isotope effect for β-hydride elimination from alkyliridium(I) complexes has bee found to be kH/kD = 2.28 ± 0.20.",

author = "John Evans and Jeffrey Schwartz and Urquhart, \{Peter W.\}",

year = "1974",

month = nov,

day = "26",

doi = "10.1016/S0022-328X(00)88213-3",

language = "English (US)",

volume = "81",

pages = "C37--C39",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "3",

}

TY - JOUR

T1 - The mechanism of β-hydride elimination from transition metal alkyls (d8)

T2 - Kinetic deuterium isotope effect

AU - Evans, John

AU - Schwartz, Jeffrey

AU - Urquhart, Peter W.

PY - 1974/11/26

Y1 - 1974/11/26

N2 - The kinetic isotope effect for β-hydride elimination from alkyliridium(I) complexes has bee found to be kH/kD = 2.28 ± 0.20.

AB - The kinetic isotope effect for β-hydride elimination from alkyliridium(I) complexes has bee found to be kH/kD = 2.28 ± 0.20.

UR - https://www.scopus.com/pages/publications/0002112037

UR - https://www.scopus.com/pages/publications/0002112037#tab=citedBy

U2 - 10.1016/S0022-328X(00)88213-3

DO - 10.1016/S0022-328X(00)88213-3

M3 - Article

AN - SCOPUS:0002112037

SN - 0022-328X

VL - 81

SP - C37-C39

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 3

ER -

The mechanism of β-hydride elimination from transition metal alkyls (d⁸): Kinetic deuterium isotope effect

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this