The Measurement of Sulfur Chemical Potential Differences Using a Calcium Fluoride Solid Electrolyte

T. A. Ramanarayanan; W. L. Worrell; T. A. Ramanarayanan

doi:10.1149/1.2129987

The Measurement of Sulfur Chemical Potential Differences Using a Calcium Fluoride Solid Electrolyte

T. A. Ramanarayanan, W. L. Worrell, T. A. Ramanarayanan

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

Calcium fluoride has been conventionally used as a solid electrolyte to measure fluorine chemical potentials in high temperature systems. However in this investigation, this electrolyte has been used as a sulfur sensor. Open-circuit emf measurements have been carried out with the following four galvanic cells The cells were investigated in the temperature range, 500°-900°C. Using Richardson and Antill's data for the standard Gibbs energy of formation of Cu₂S, the standard Gibbs energies of formation of FeS, Ag₂S, MnS, and CrS have been determined.

Original language	English (US)
Pages (from-to)	1717-1721
Number of pages	5
Journal	Journal of the Electrochemical Society
Volume	127
Issue number	8
DOIs	https://doi.org/10.1149/1.2129987
State	Published - 1980
Externally published	Yes

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Materials Chemistry
Surfaces, Coatings and Films
Electrochemistry
Renewable Energy, Sustainability and the Environment

Keywords

emf measurements
solid electrolyte
sulfur sensor

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10.1149/1.2129987

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abstract = "Calcium fluoride has been conventionally used as a solid electrolyte to measure fluorine chemical potentials in high temperature systems. However in this investigation, this electrolyte has been used as a sulfur sensor. Open-circuit emf measurements have been carried out with the following four galvanic cells The cells were investigated in the temperature range, 500°-900°C. Using Richardson and Antill's data for the standard Gibbs energy of formation of Cu2S, the standard Gibbs energies of formation of FeS, Ag2S, MnS, and CrS have been determined.",

keywords = "emf measurements, solid electrolyte, sulfur sensor",

author = "Ramanarayanan, \{T. A.\} and Worrell, \{W. L.\} and Ramanarayanan, \{T. A.\}",

year = "1980",

doi = "10.1149/1.2129987",

language = "English (US)",

volume = "127",

pages = "1717--1721",

journal = "Journal of the Electrochemical Society",

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T1 - The Measurement of Sulfur Chemical Potential Differences Using a Calcium Fluoride Solid Electrolyte

AU - Ramanarayanan, T. A.

AU - Worrell, W. L.

AU - Ramanarayanan, T. A.

PY - 1980

Y1 - 1980

N2 - Calcium fluoride has been conventionally used as a solid electrolyte to measure fluorine chemical potentials in high temperature systems. However in this investigation, this electrolyte has been used as a sulfur sensor. Open-circuit emf measurements have been carried out with the following four galvanic cells The cells were investigated in the temperature range, 500°-900°C. Using Richardson and Antill's data for the standard Gibbs energy of formation of Cu2S, the standard Gibbs energies of formation of FeS, Ag2S, MnS, and CrS have been determined.

AB - Calcium fluoride has been conventionally used as a solid electrolyte to measure fluorine chemical potentials in high temperature systems. However in this investigation, this electrolyte has been used as a sulfur sensor. Open-circuit emf measurements have been carried out with the following four galvanic cells The cells were investigated in the temperature range, 500°-900°C. Using Richardson and Antill's data for the standard Gibbs energy of formation of Cu2S, the standard Gibbs energies of formation of FeS, Ag2S, MnS, and CrS have been determined.

KW - emf measurements

KW - solid electrolyte

KW - sulfur sensor

UR - https://www.scopus.com/pages/publications/0019049747

UR - https://www.scopus.com/inward/citedby.url?scp=0019049747&partnerID=8YFLogxK

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DO - 10.1149/1.2129987

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SN - 0013-4651

VL - 127

SP - 1717

EP - 1721

JO - Journal of the Electrochemical Society

JF - Journal of the Electrochemical Society

IS - 8

ER -

The Measurement of Sulfur Chemical Potential Differences Using a Calcium Fluoride Solid Electrolyte

Abstract

All Science Journal Classification (ASJC) codes

Keywords

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