The layered RuBr3-RuI3 honeycomb system

Danrui Ni, Xianghan Xu, Robert J. Cava

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

The layered RuBr3-RuI3 honeycomb structure solid solution was synthesized at high pressures. The crystal structures are centrosymmetric (space group R3̄) and based on honeycomb layers of spin ½ Ru3+. The solid solution switches from insulating to metallic between RuBr0.75I2.25 and RuBr0.50I2.50. A preliminary structure/property phase diagram is presented. Our results suggest that this solid solution may provide insight into the influence of disorder on spin-orbit-coupled quantum spin liquids.

Original languageEnglish (US)
Pages (from-to)4897-4903
Number of pages7
JournalJournal of Materials Chemistry C
Volume12
Issue number13
DOIs
StatePublished - Mar 11 2024

All Science Journal Classification (ASJC) codes

  • General Chemistry
  • Materials Chemistry

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