The influence of ligand bite angle on the enantioselectivity of copper(II)-catalysed Diels-Alder reactions

Ian W. Davies; Linda Gerena; Laurie Castonguay; Chris H. Senanayake; Robert D. Larsen; Thomas R. Verhoeven; Paul J. Reider

doi:10.1039/CC9960001753

The influence of ligand bite angle on the enantioselectivity of copper(II)-catalysed Diels-Alder reactions

Ian W. Davies
, Linda Gerena
, Laurie Castonguay
, Chris H. Senanayake
, Robert D. Larsen
, Thomas R. Verhoeven
, Paul J. Reider

Research output: Contribution to journal › Article › peer-review

124 Scopus citations

Abstract

Novel spirobis(oxazolines) provide excellent levels of stereocontrol in copper-catalysed Diels-Alder reactions; the larger the ligand bite angle the higher the enantioselection (up to 98.4% ee).

Original language	English (US)
Pages (from-to)	1753-1754
Number of pages	2
Journal	Chemical Communications
Issue number	15
DOIs	https://doi.org/10.1039/CC9960001753
State	Published - 1996
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/CC9960001753

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@article{a5116794cf6047cf9bd612e3863816d1,

title = "The influence of ligand bite angle on the enantioselectivity of copper(II)-catalysed Diels-Alder reactions",

abstract = "Novel spirobis(oxazolines) provide excellent levels of stereocontrol in copper-catalysed Diels-Alder reactions; the larger the ligand bite angle the higher the enantioselection (up to 98.4\% ee).",

author = "Davies, \{Ian W.\} and Linda Gerena and Laurie Castonguay and Senanayake, \{Chris H.\} and Larsen, \{Robert D.\} and Verhoeven, \{Thomas R.\} and Reider, \{Paul J.\}",

year = "1996",

doi = "10.1039/CC9960001753",

language = "English (US)",

pages = "1753--1754",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "15",

}

TY - JOUR

T1 - The influence of ligand bite angle on the enantioselectivity of copper(II)-catalysed Diels-Alder reactions

AU - Davies, Ian W.

AU - Gerena, Linda

AU - Castonguay, Laurie

AU - Senanayake, Chris H.

AU - Larsen, Robert D.

AU - Verhoeven, Thomas R.

AU - Reider, Paul J.

PY - 1996

Y1 - 1996

N2 - Novel spirobis(oxazolines) provide excellent levels of stereocontrol in copper-catalysed Diels-Alder reactions; the larger the ligand bite angle the higher the enantioselection (up to 98.4% ee).

AB - Novel spirobis(oxazolines) provide excellent levels of stereocontrol in copper-catalysed Diels-Alder reactions; the larger the ligand bite angle the higher the enantioselection (up to 98.4% ee).

UR - https://www.scopus.com/pages/publications/0001929811

UR - https://www.scopus.com/pages/publications/0001929811#tab=citedBy

U2 - 10.1039/CC9960001753

DO - 10.1039/CC9960001753

M3 - Article

AN - SCOPUS:0001929811

SN - 1359-7345

SP - 1753

EP - 1754

JO - Chemical Communications

JF - Chemical Communications

IS - 15

ER -

The influence of ligand bite angle on the enantioselectivity of copper(II)-catalysed Diels-Alder reactions

Abstract

All Science Journal Classification (ASJC) codes

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