The importance of cyclopentadienyl substituent effects in group 4 metallocene dinitrogen chemistry

Jaime A. Pool, Paul J. Chirik

Research output: Contribution to journalArticle

32 Scopus citations

Abstract

This article highlights some of our recent efforts and presents new data on the importance of cyclopentadienyl substituent effects on group 4 metallocene dinitrogen chemistry. Reactions such as the coordination of N2 to an isolated titanium sandwich complex, alkali-metal reductions of zirconocene dihalide complexes, alkane reductive elimination reactions, and the hydrogenation of zirconium dinitrogen complexes are all extremely sensitive to the groups present on the cyclopentadienyl rings. These results are promising for the future of N2 fixation, as the reactivity of a specific metallocene can be dramatically altered by subtle manipulations in ligand substituents.

Original languageEnglish (US)
Pages (from-to)286-295
Number of pages10
JournalCanadian Journal of Chemistry
Volume83
Issue number4
DOIs
StatePublished - Apr 1 2005
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Organic Chemistry

Keywords

  • Ammonia
  • Cyclopentadienyl
  • Dinitrogen
  • Sandwich
  • Zirconium

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