The Effect of propargyl oxygen substituents in the carbene-chromium/alkyne cycloaddition

M. F. Semmelhack; Nakcheol Jeong; Gary R. Lee

doi:10.1016/S0040-4039(00)94580-5

The Effect of propargyl oxygen substituents in the carbene-chromium/alkyne cycloaddition

M. F. Semmelhack, Nakcheol Jeong, Gary R. Lee

Chemistry

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

The usual reaction of alkalynes with arylcarbene chromium complexes is deflected by hte presence of propargylic alkoxy groups, especially in the case of the 2,5-dimethoxypnenyl carbene ligand; indenes and furans become significant products.

Original language	English (US)
Pages (from-to)	609-610
Number of pages	2
Journal	Tetrahedron Letters
Volume	31
Issue number	5
DOIs	https://doi.org/10.1016/S0040-4039(00)94580-5
State	Published - 1990

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)94580-5

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title = "The Effect of propargyl oxygen substituents in the carbene-chromium/alkyne cycloaddition",

abstract = "The usual reaction of alkalynes with arylcarbene chromium complexes is deflected by hte presence of propargylic alkoxy groups, especially in the case of the 2,5-dimethoxypnenyl carbene ligand; indenes and furans become significant products.",

author = "Semmelhack, {M. F.} and Nakcheol Jeong and Lee, {Gary R.}",

year = "1990",

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journal = "Tetrahedron Letters",

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AU - Semmelhack, M. F.

AU - Jeong, Nakcheol

AU - Lee, Gary R.

PY - 1990

Y1 - 1990

N2 - The usual reaction of alkalynes with arylcarbene chromium complexes is deflected by hte presence of propargylic alkoxy groups, especially in the case of the 2,5-dimethoxypnenyl carbene ligand; indenes and furans become significant products.

AB - The usual reaction of alkalynes with arylcarbene chromium complexes is deflected by hte presence of propargylic alkoxy groups, especially in the case of the 2,5-dimethoxypnenyl carbene ligand; indenes and furans become significant products.

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U2 - 10.1016/S0040-4039(00)94580-5

DO - 10.1016/S0040-4039(00)94580-5

M3 - Article

AN - SCOPUS:0025008612

SN - 0040-4039

VL - 31

SP - 609

EP - 610

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 5

ER -

The Effect of propargyl oxygen substituents in the carbene-chromium/alkyne cycloaddition

Abstract

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