The A2+Mn5(SO4)6 family of triangular lattice, ferrimagnetic sulfates

D. V. West; T. M. McQueen; I. D. Posen; X. Ke; Q. Huang; H. W. Zandbergen; A. J. Williams; P. Schiffer; R. J. Cava

doi:10.1016/j.jssc.2009.03.001

The A²⁺Mn₅(SO₄)₆ family of triangular lattice, ferrimagnetic sulfates

D. V. West
, T. M. McQueen
, I. D. Posen
, X. Ke
, Q. Huang
, H. W. Zandbergen
, A. J. Williams
, P. Schiffer
, R. J. Cava

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

A new family of anhydrous sulfates, A²⁺Mn₅(SO₄)₆ (A=Pb, Ba, Sr) is reported. The crystal structures of PbMn₅(SO₄)₆ and SrMn₅(SO₄)₆ are solved by powder X-ray and neutron diffraction. BaMn₅(SO₄)₆ is isostructural. PbMn₅(SO₄)₆ crystallizes with P over(3, -) symmetry and unit cell parameters of a=14.551(1) Å and c=7.535(1) Å. The structure has rich features, including dimers of face-sharing MnO₆ octahedra, and two complementary triangular layers of Mn atoms. All compounds undergo a magnetic ordering transition at 10 K, below which, the magnetic susceptibility of the compounds varies systematically with the radius of the non-magnetic cation. Low temperature neutron diffraction shows that the complementary triangular layers result in a ferrimagnet with a net moment corresponding to one high spin Mn²⁺ per unit cell, correlating well with the magnetization data. The non-magnetic variant PbMg₅(SO₄)₆ is also reported.

Original language	English (US)
Pages (from-to)	1343-1350
Number of pages	8
Journal	Journal of Solid State Chemistry
Volume	182
Issue number	6
DOIs	https://doi.org/10.1016/j.jssc.2009.03.001
State	Published - Jun 2009

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Keywords

Crystallography
Geometric frustration
Magnetism
New crystal structure
Regular polygon tiling
Sulfate
Triangular lattice

Access to Document

10.1016/j.jssc.2009.03.001

Cite this

@article{f13c5ebdd2d24b189df3f91f21409295,

title = "The A2+Mn5(SO4)6 family of triangular lattice, ferrimagnetic sulfates",

abstract = "A new family of anhydrous sulfates, A2+Mn5(SO4)6 (A=Pb, Ba, Sr) is reported. The crystal structures of PbMn5(SO4)6 and SrMn5(SO4)6 are solved by powder X-ray and neutron diffraction. BaMn5(SO4)6 is isostructural. PbMn5(SO4)6 crystallizes with P over(3, -) symmetry and unit cell parameters of a=14.551(1) {\AA} and c=7.535(1) {\AA}. The structure has rich features, including dimers of face-sharing MnO6 octahedra, and two complementary triangular layers of Mn atoms. All compounds undergo a magnetic ordering transition at 10 K, below which, the magnetic susceptibility of the compounds varies systematically with the radius of the non-magnetic cation. Low temperature neutron diffraction shows that the complementary triangular layers result in a ferrimagnet with a net moment corresponding to one high spin Mn2+ per unit cell, correlating well with the magnetization data. The non-magnetic variant PbMg5(SO4)6 is also reported.",

keywords = "Crystallography, Geometric frustration, Magnetism, New crystal structure, Regular polygon tiling, Sulfate, Triangular lattice",

author = "West, \{D. V.\} and McQueen, \{T. M.\} and Posen, \{I. D.\} and X. Ke and Q. Huang and Zandbergen, \{H. W.\} and Williams, \{A. J.\} and P. Schiffer and Cava, \{R. J.\}",

note = "Funding Information: This research was supported by the NSF grant number DMR-0701582, and by the NSF program in Solid State Chemistry, grant number NSF DMR-0703095. Certain commercial materials and equipment are identified in this report to describe the subject adequately. Such identification does not imply recommendation or endorsement by the NIST, nor does it imply that the materials and equipment identified are necessarily the best available for the purpose. T.M. McQueen gratefully acknowledges support of the National Science Foundation Graduate Research Fellowship Program. Copyright: Copyright 2009 Elsevier B.V., All rights reserved.",

year = "2009",

month = jun,

doi = "10.1016/j.jssc.2009.03.001",

language = "English (US)",

volume = "182",

pages = "1343--1350",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

number = "6",

}

TY - JOUR

T1 - The A2+Mn5(SO4)6 family of triangular lattice, ferrimagnetic sulfates

AU - West, D. V.

AU - McQueen, T. M.

AU - Posen, I. D.

AU - Ke, X.

AU - Huang, Q.

AU - Zandbergen, H. W.

AU - Williams, A. J.

AU - Schiffer, P.

AU - Cava, R. J.

N1 - Funding Information: This research was supported by the NSF grant number DMR-0701582, and by the NSF program in Solid State Chemistry, grant number NSF DMR-0703095. Certain commercial materials and equipment are identified in this report to describe the subject adequately. Such identification does not imply recommendation or endorsement by the NIST, nor does it imply that the materials and equipment identified are necessarily the best available for the purpose. T.M. McQueen gratefully acknowledges support of the National Science Foundation Graduate Research Fellowship Program. Copyright: Copyright 2009 Elsevier B.V., All rights reserved.

PY - 2009/6

Y1 - 2009/6

N2 - A new family of anhydrous sulfates, A2+Mn5(SO4)6 (A=Pb, Ba, Sr) is reported. The crystal structures of PbMn5(SO4)6 and SrMn5(SO4)6 are solved by powder X-ray and neutron diffraction. BaMn5(SO4)6 is isostructural. PbMn5(SO4)6 crystallizes with P over(3, -) symmetry and unit cell parameters of a=14.551(1) Å and c=7.535(1) Å. The structure has rich features, including dimers of face-sharing MnO6 octahedra, and two complementary triangular layers of Mn atoms. All compounds undergo a magnetic ordering transition at 10 K, below which, the magnetic susceptibility of the compounds varies systematically with the radius of the non-magnetic cation. Low temperature neutron diffraction shows that the complementary triangular layers result in a ferrimagnet with a net moment corresponding to one high spin Mn2+ per unit cell, correlating well with the magnetization data. The non-magnetic variant PbMg5(SO4)6 is also reported.

AB - A new family of anhydrous sulfates, A2+Mn5(SO4)6 (A=Pb, Ba, Sr) is reported. The crystal structures of PbMn5(SO4)6 and SrMn5(SO4)6 are solved by powder X-ray and neutron diffraction. BaMn5(SO4)6 is isostructural. PbMn5(SO4)6 crystallizes with P over(3, -) symmetry and unit cell parameters of a=14.551(1) Å and c=7.535(1) Å. The structure has rich features, including dimers of face-sharing MnO6 octahedra, and two complementary triangular layers of Mn atoms. All compounds undergo a magnetic ordering transition at 10 K, below which, the magnetic susceptibility of the compounds varies systematically with the radius of the non-magnetic cation. Low temperature neutron diffraction shows that the complementary triangular layers result in a ferrimagnet with a net moment corresponding to one high spin Mn2+ per unit cell, correlating well with the magnetization data. The non-magnetic variant PbMg5(SO4)6 is also reported.

KW - Crystallography

KW - Geometric frustration

KW - Magnetism

KW - New crystal structure

KW - Regular polygon tiling

KW - Sulfate

KW - Triangular lattice

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U2 - 10.1016/j.jssc.2009.03.001

DO - 10.1016/j.jssc.2009.03.001

M3 - Article

AN - SCOPUS:67349117868

SN - 0022-4596

VL - 182

SP - 1343

EP - 1350

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

IS - 6

ER -