T-matrix scaling relations: Necessary and sufficient conditions for the existence of dynamically invariant scaling coefficients

Larry Eno, Britton Chang, Herschel Rabitz

Research output: Contribution to journalArticle

2 Scopus citations

Abstract

It is well established that a multiplicative in internal coordinates transition operator is a sufficient condition for the existence of dynamically invariant scaling coefficients. Here we show that by defining the dynamical invariance of the scaling coefficients with respect to a Lippman-Schwinger equation of motion, the same multiplicative in internal coordinates transition operator arises as a necessary condition.

Original languageEnglish (US)
Pages (from-to)2598-2601
Number of pages4
JournalThe Journal of chemical physics
Volume80
Issue number6
DOIs
StatePublished - 1983

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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