Abstract
Two novel dihydropyrroloindoledione (DPID)-based copolymers have been synthesized in a two directional approach and characterized (gel permeation chromatography (GPC), ultraviolet-visible (UV-vis), cyclic voltammetry, and computational models). These planar, broad absorption copolymers show promise for use in organic electronics, with deep energy levels and low bandgaps. The two-directional Knoevenagel condensation used demonstrates the versatility of DPID as a useful yet underexploited conjugated unit.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 1285-1291 |
| Number of pages | 7 |
| Journal | Journal of Polymer Science, Part A: Polymer Chemistry |
| Volume | 51 |
| Issue number | 6 |
| DOIs | |
| State | Published - Mar 15 2013 |
| Externally published | Yes |
All Science Journal Classification (ASJC) codes
- Polymers and Plastics
- Organic Chemistry
- Materials Chemistry
Keywords
- Knoevenagel condensation
- Pummerer-type cyclization
- conjugated polymer
- copolymerization
- dihydropyrroloindoledione
- organic electronics
- synthesis
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