Synthesis of three layer Na xCoO 2 (x=0.3, 0.5, 0.6, 0.75, 1.0) and superconductivity in three layer Na 0.3CoO 2•1.3H 2O

M. L. Foo; T. Klimczuk; L. Li; N. P. Ong; R. J. Cava; Q. Huang; J. W. Lynn; H. W. Zandbergen

Synthesis of three layer Na _xCoO ₂ (x=0.3, 0.5, 0.6, 0.75, 1.0) and superconductivity in three layer Na _0.3CoO ₂•1.3H ₂O

M. L. Foo, T. Klimczuk, L. Li, N. P. Ong, R. J. Cava, Q. Huang, J. W. Lynn, H. W. Zandbergen

Research output: Contribution to journal › Conference article › peer-review

Abstract

The synthesis of three layer sodium cobalt oxide, Na _xCoO ₂ (x=0.3, 0.5, 0.6, 0.75 and 1.0) is reported. For x=0.6, 0.75, and 1.0, conventional solid-state synthesis was employed. x=0.3 and 0.5 were obtained via oxidative deintercalation of sodium at room temperature. x=0.3 can be hydrated to Na _0.3CoO ₂•1.3H ₂O which is superconducting with a T _c of 4.3 K. Although having the same chemical stiochiometry as the previously reported two layer superconductor, it has a different stacking sequence of CoO ₂ layers making it structurally distinct. Crystals of three layer NaCoO ₂ show triangular morphology compared to hexagonal morphology for two layer Na _0.7CoO ₂.

Original language	English (US)
Article number	FF6.11
Pages (from-to)	275-280
Number of pages	6
Journal	Materials Research Society Symposium Proceedings
Volume	848
State	Published - 2005
Event	2004 Materials Research Society Fall Meeting - Boston, MA, United States Duration: Nov 29 2004 → Dec 2 2004

All Science Journal Classification (ASJC) codes

General Materials Science
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

Cite this

@article{e0b270f1311446ae9899349124369d20,

title = "Synthesis of three layer Na xCoO 2 (x=0.3, 0.5, 0.6, 0.75, 1.0) and superconductivity in three layer Na 0.3CoO 2•1.3H 2O",

abstract = "The synthesis of three layer sodium cobalt oxide, Na xCoO 2 (x=0.3, 0.5, 0.6, 0.75 and 1.0) is reported. For x=0.6, 0.75, and 1.0, conventional solid-state synthesis was employed. x=0.3 and 0.5 were obtained via oxidative deintercalation of sodium at room temperature. x=0.3 can be hydrated to Na 0.3CoO 2•1.3H 2O which is superconducting with a T c of 4.3 K. Although having the same chemical stiochiometry as the previously reported two layer superconductor, it has a different stacking sequence of CoO 2 layers making it structurally distinct. Crystals of three layer NaCoO 2 show triangular morphology compared to hexagonal morphology for two layer Na 0.7CoO 2.",

author = "Foo, {M. L.} and T. Klimczuk and L. Li and Ong, {N. P.} and Cava, {R. J.} and Q. Huang and Lynn, {J. W.} and Zandbergen, {H. W.}",

year = "2005",

language = "English (US)",

volume = "848",

pages = "275--280",

journal = "Materials Research Society Symposium Proceedings",

issn = "0272-9172",

publisher = "Materials Research Society",

note = "2004 Materials Research Society Fall Meeting ; Conference date: 29-11-2004 Through 02-12-2004",

}

TY - JOUR

T1 - Synthesis of three layer Na xCoO 2 (x=0.3, 0.5, 0.6, 0.75, 1.0) and superconductivity in three layer Na 0.3CoO 2•1.3H 2O

AU - Foo, M. L.

AU - Klimczuk, T.

AU - Li, L.

AU - Ong, N. P.

AU - Cava, R. J.

AU - Huang, Q.

AU - Lynn, J. W.

AU - Zandbergen, H. W.

PY - 2005

Y1 - 2005

N2 - The synthesis of three layer sodium cobalt oxide, Na xCoO 2 (x=0.3, 0.5, 0.6, 0.75 and 1.0) is reported. For x=0.6, 0.75, and 1.0, conventional solid-state synthesis was employed. x=0.3 and 0.5 were obtained via oxidative deintercalation of sodium at room temperature. x=0.3 can be hydrated to Na 0.3CoO 2•1.3H 2O which is superconducting with a T c of 4.3 K. Although having the same chemical stiochiometry as the previously reported two layer superconductor, it has a different stacking sequence of CoO 2 layers making it structurally distinct. Crystals of three layer NaCoO 2 show triangular morphology compared to hexagonal morphology for two layer Na 0.7CoO 2.

AB - The synthesis of three layer sodium cobalt oxide, Na xCoO 2 (x=0.3, 0.5, 0.6, 0.75 and 1.0) is reported. For x=0.6, 0.75, and 1.0, conventional solid-state synthesis was employed. x=0.3 and 0.5 were obtained via oxidative deintercalation of sodium at room temperature. x=0.3 can be hydrated to Na 0.3CoO 2•1.3H 2O which is superconducting with a T c of 4.3 K. Although having the same chemical stiochiometry as the previously reported two layer superconductor, it has a different stacking sequence of CoO 2 layers making it structurally distinct. Crystals of three layer NaCoO 2 show triangular morphology compared to hexagonal morphology for two layer Na 0.7CoO 2.

UR - http://www.scopus.com/inward/record.url?scp=28844432073&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=28844432073&partnerID=8YFLogxK

M3 - Conference article

AN - SCOPUS:28844432073

SN - 0272-9172

VL - 848

SP - 275

EP - 280

JO - Materials Research Society Symposium Proceedings

JF - Materials Research Society Symposium Proceedings

M1 - FF6.11

T2 - 2004 Materials Research Society Fall Meeting

Y2 - 29 November 2004 through 2 December 2004

ER -

Synthesis of three layer Na _xCoO ₂ (x=0.3, 0.5, 0.6, 0.75, 1.0) and superconductivity in three layer Na _0.3CoO ₂•1.3H ₂O

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All Science Journal Classification (ASJC) codes

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