Synthesis of the amino sugar from C-1027

M. F. Semmelhack, Yu Jiang, Douglas Ho

Research output: Contribution to journalArticlepeer-review

19 Scopus citations

Abstract

(matrix presented) The amino sugar side chain (2) from C-1027Chr was synthesized in 12 steps from mannose. The key reactions are an internal displacement by nitrogen to introduce the cis amino group at C-4 and the methylation of an enolate at C-5.

Original languageEnglish (US)
Pages (from-to)2403-2406
Number of pages4
JournalOrganic letters
Volume3
Issue number15
DOIs
StatePublished - Jul 26 2001

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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