Synthesis of novel thieno[3,2-b]thienobis(silolothiophene) based low bandgap polymers for organic photovoltaics

Bob C. Schroeder; Raja Shahid Ashraf; Stuart Thomas; Andrew J.P. White; Laure Biniek; Christian B. Nielsen; Weimin Zhang; Zhenggang Huang; Pabitra Shakya Tuladhar; Scott E. Watkins; Thomas D. Anthopoulos; James R. Durrant; Iain McCulloch

doi:10.1039/c2cc33718e

Synthesis of novel thieno[3,2-b]thienobis(silolothiophene) based low bandgap polymers for organic photovoltaics

Bob C. Schroeder
, Raja Shahid Ashraf
, Stuart Thomas
, Andrew J.P. White
, Laure Biniek
, Christian B. Nielsen
, Weimin Zhang
, Zhenggang Huang
, Pabitra Shakya Tuladhar
, Scott E. Watkins
, Thomas D. Anthopoulos
, James R. Durrant
, Iain McCulloch

Research output: Contribution to journal › Article › peer-review

60 Scopus citations

Abstract

Thieno[3,2-b]thienobis(silolothiophene), a new electron rich hexacyclic monomer has been synthesized and incorporated into three novel donor–acceptor low-bandgap polymers. By carefully choosing the acceptor co-monomer, the energy levels of the polymers could be modulated and high power conversion efficiencies of 5.52% were reached in OPV devices.

Original language	English (US)
Pages (from-to)	7699-7701
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	62
DOIs	https://doi.org/10.1039/c2cc33718e
State	Published - Jul 9 2012
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c2cc33718e

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Schroeder, B. C., Shahid Ashraf, R., Thomas, S., White, A. J. P., Biniek, L., Nielsen, C. B., Zhang, W., Huang, Z., Shakya Tuladhar, P., Watkins, S. E., Anthopoulos, T. D., Durrant, J. R., & McCulloch, I. (2012). Synthesis of novel thieno[3,2-b]thienobis(silolothiophene) based low bandgap polymers for organic photovoltaics. Chemical Communications, 48(62), 7699-7701. https://doi.org/10.1039/c2cc33718e

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title = "Synthesis of novel thieno[3,2-b]thienobis(silolothiophene) based low bandgap polymers for organic photovoltaics",

abstract = "Thieno[3,2-b]thienobis(silolothiophene), a new electron rich hexacyclic monomer has been synthesized and incorporated into three novel donor–acceptor low-bandgap polymers. By carefully choosing the acceptor co-monomer, the energy levels of the polymers could be modulated and high power conversion efficiencies of 5.52\% were reached in OPV devices.",

author = "Schroeder, \{Bob C.\} and \{Shahid Ashraf\}, Raja and Stuart Thomas and White, \{Andrew J.P.\} and Laure Biniek and Nielsen, \{Christian B.\} and Weimin Zhang and Zhenggang Huang and \{Shakya Tuladhar\}, Pabitra and Watkins, \{Scott E.\} and Anthopoulos, \{Thomas D.\} and Durrant, \{James R.\} and Iain McCulloch",

year = "2012",

month = jul,

day = "9",

doi = "10.1039/c2cc33718e",

language = "English (US)",

volume = "48",

pages = "7699--7701",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "62",

}

Schroeder, BC, Shahid Ashraf, R, Thomas, S, White, AJP, Biniek, L, Nielsen, CB, Zhang, W, Huang, Z, Shakya Tuladhar, P, Watkins, SE, Anthopoulos, TD, Durrant, JR & McCulloch, I 2012, 'Synthesis of novel thieno[3,2-b]thienobis(silolothiophene) based low bandgap polymers for organic photovoltaics', Chemical Communications, vol. 48, no. 62, pp. 7699-7701. https://doi.org/10.1039/c2cc33718e

TY - JOUR

T1 - Synthesis of novel thieno[3,2-b]thienobis(silolothiophene) based low bandgap polymers for organic photovoltaics

AU - Schroeder, Bob C.

AU - Shahid Ashraf, Raja

AU - Thomas, Stuart

AU - White, Andrew J.P.

AU - Biniek, Laure

AU - Nielsen, Christian B.

AU - Zhang, Weimin

AU - Huang, Zhenggang

AU - Shakya Tuladhar, Pabitra

AU - Watkins, Scott E.

AU - Anthopoulos, Thomas D.

AU - Durrant, James R.

AU - McCulloch, Iain

PY - 2012/7/9

Y1 - 2012/7/9

N2 - Thieno[3,2-b]thienobis(silolothiophene), a new electron rich hexacyclic monomer has been synthesized and incorporated into three novel donor–acceptor low-bandgap polymers. By carefully choosing the acceptor co-monomer, the energy levels of the polymers could be modulated and high power conversion efficiencies of 5.52% were reached in OPV devices.

AB - Thieno[3,2-b]thienobis(silolothiophene), a new electron rich hexacyclic monomer has been synthesized and incorporated into three novel donor–acceptor low-bandgap polymers. By carefully choosing the acceptor co-monomer, the energy levels of the polymers could be modulated and high power conversion efficiencies of 5.52% were reached in OPV devices.

UR - https://www.scopus.com/pages/publications/84863918010

UR - https://www.scopus.com/pages/publications/84863918010#tab=citedBy

U2 - 10.1039/c2cc33718e

DO - 10.1039/c2cc33718e

M3 - Article

C2 - 22751079

AN - SCOPUS:84863918010

SN - 1359-7345

VL - 48

SP - 7699

EP - 7701

JO - Chemical Communications

JF - Chemical Communications

IS - 62

ER -

Synthesis of novel thieno[3,2-b]thienobis(silolothiophene) based low bandgap polymers for organic photovoltaics

Abstract

All Science Journal Classification (ASJC) codes

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