Synthesis of novel thieno[3,2-b]thienobis(silolothiophene) based low bandgap polymers for organic photovoltaics

Bob C. Schroeder; Raja Shahid Ashraf; Stuart Thomas; Andrew J.P. White; Laure Biniek; Christian B. Nielsen; Weimin Zhang; Zhenggang Huang; Pabitra Shakya Tuladhar; Scott E. Watkins; Thomas D. Anthopoulos; James R. Durrant; Iain McCulloch

doi:10.1039/c2cc33718e

Synthesis of novel thieno[3,2-b]thienobis(silolothiophene) based low bandgap polymers for organic photovoltaics

Bob C. Schroeder, Raja Shahid Ashraf, Stuart Thomas, Andrew J.P. White, Laure Biniek, Christian B. Nielsen, Weimin Zhang, Zhenggang Huang, Pabitra Shakya Tuladhar, Scott E. Watkins, Thomas D. Anthopoulos, James R. Durrant, Iain McCulloch

Research output: Contribution to journal › Article › peer-review

60 Scopus citations

Abstract

Thieno[3,2-b]thienobis(silolothiophene), a new electron rich hexacyclic monomer has been synthesized and incorporated into three novel donor–acceptor low-bandgap polymers. By carefully choosing the acceptor co-monomer, the energy levels of the polymers could be modulated and high power conversion efficiencies of 5.52% were reached in OPV devices.

Original language	English (US)
Pages (from-to)	7699-7701
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	62
DOIs	https://doi.org/10.1039/c2cc33718e
State	Published - Jul 9 2012
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c2cc33718e

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Schroeder, B. C., Shahid Ashraf, R., Thomas, S., White, A. J. P., Biniek, L., Nielsen, C. B., Zhang, W., Huang, Z., Shakya Tuladhar, P., Watkins, S. E., Anthopoulos, T. D., Durrant, J. R., & McCulloch, I. (2012). Synthesis of novel thieno[3,2-b]thienobis(silolothiophene) based low bandgap polymers for organic photovoltaics. Chemical Communications, 48(62), 7699-7701. https://doi.org/10.1039/c2cc33718e

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title = "Synthesis of novel thieno[3,2-b]thienobis(silolothiophene) based low bandgap polymers for organic photovoltaics",

abstract = "Thieno[3,2-b]thienobis(silolothiophene), a new electron rich hexacyclic monomer has been synthesized and incorporated into three novel donor–acceptor low-bandgap polymers. By carefully choosing the acceptor co-monomer, the energy levels of the polymers could be modulated and high power conversion efficiencies of 5.52\% were reached in OPV devices.",

author = "Schroeder, \{Bob C.\} and \{Shahid Ashraf\}, Raja and Stuart Thomas and White, \{Andrew J.P.\} and Laure Biniek and Nielsen, \{Christian B.\} and Weimin Zhang and Zhenggang Huang and \{Shakya Tuladhar\}, Pabitra and Watkins, \{Scott E.\} and Anthopoulos, \{Thomas D.\} and Durrant, \{James R.\} and Iain McCulloch",

year = "2012",

month = jul,

day = "9",

doi = "10.1039/c2cc33718e",

language = "English (US)",

volume = "48",

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journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

number = "62",

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Schroeder, BC, Shahid Ashraf, R, Thomas, S, White, AJP, Biniek, L, Nielsen, CB, Zhang, W, Huang, Z, Shakya Tuladhar, P, Watkins, SE, Anthopoulos, TD, Durrant, JR & McCulloch, I 2012, 'Synthesis of novel thieno[3,2-b]thienobis(silolothiophene) based low bandgap polymers for organic photovoltaics', Chemical Communications, vol. 48, no. 62, pp. 7699-7701. https://doi.org/10.1039/c2cc33718e

TY - JOUR

T1 - Synthesis of novel thieno[3,2-b]thienobis(silolothiophene) based low bandgap polymers for organic photovoltaics

AU - Schroeder, Bob C.

AU - Shahid Ashraf, Raja

AU - Thomas, Stuart

AU - White, Andrew J.P.

AU - Biniek, Laure

AU - Nielsen, Christian B.

AU - Zhang, Weimin

AU - Huang, Zhenggang

AU - Shakya Tuladhar, Pabitra

AU - Watkins, Scott E.

AU - Anthopoulos, Thomas D.

AU - Durrant, James R.

AU - McCulloch, Iain

PY - 2012/7/9

Y1 - 2012/7/9

N2 - Thieno[3,2-b]thienobis(silolothiophene), a new electron rich hexacyclic monomer has been synthesized and incorporated into three novel donor–acceptor low-bandgap polymers. By carefully choosing the acceptor co-monomer, the energy levels of the polymers could be modulated and high power conversion efficiencies of 5.52% were reached in OPV devices.

AB - Thieno[3,2-b]thienobis(silolothiophene), a new electron rich hexacyclic monomer has been synthesized and incorporated into three novel donor–acceptor low-bandgap polymers. By carefully choosing the acceptor co-monomer, the energy levels of the polymers could be modulated and high power conversion efficiencies of 5.52% were reached in OPV devices.

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DO - 10.1039/c2cc33718e

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AN - SCOPUS:84863918010

SN - 1359-7345

VL - 48

SP - 7699

EP - 7701

JO - Chemical Communications

JF - Chemical Communications

IS - 62

ER -

Synthesis of novel thieno[3,2-b]thienobis(silolothiophene) based low bandgap polymers for organic photovoltaics

Abstract

All Science Journal Classification (ASJC) codes

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