Synthesis of mesostructured nickel oxide with silica

Xinghua Liu; C. M. Chun; Ilhan A. Aksay; Wei Heng Shih

doi:10.1021/ie990129l

Synthesis of mesostructured nickel oxide with silica

Xinghua Liu, C. M. Chun, Ilhan A. Aksay, Wei Heng Shih

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28 Scopus citations

Abstract

Mesostructured nickel oxide was formed with nickel sulfate and cationic surfactant cetyltrim-ethylammonium bromide (CTAB). X-ray diffraction (XRD) peaks at low scattering angles and transmission electron microscopy (TEM) indicated that a mesostructure was formed. However, these XRD patterns disappeared after calcination. The addition of sodium silicate in the precursor solutions produced a mesostructure, which is stable against calcination. Surface areas as high as 530 m²/g can be obtained for the nickel silicate mesophase. TEM-EDXS showed that the Si/Ni molar ratio in the mesophase is ~0.5, independent of the initial Si/Ni ratio in the precursor.

Original language	English (US)
Pages (from-to)	684-692
Number of pages	9
Journal	Industrial and Engineering Chemistry Research
Volume	39
Issue number	3
DOIs	https://doi.org/10.1021/ie990129l
State	Published - 2000

All Science Journal Classification (ASJC) codes

General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering

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10.1021/ie990129l

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title = "Synthesis of mesostructured nickel oxide with silica",

abstract = "Mesostructured nickel oxide was formed with nickel sulfate and cationic surfactant cetyltrim-ethylammonium bromide (CTAB). X-ray diffraction (XRD) peaks at low scattering angles and transmission electron microscopy (TEM) indicated that a mesostructure was formed. However, these XRD patterns disappeared after calcination. The addition of sodium silicate in the precursor solutions produced a mesostructure, which is stable against calcination. Surface areas as high as 530 m2/g can be obtained for the nickel silicate mesophase. TEM-EDXS showed that the Si/Ni molar ratio in the mesophase is ~0.5, independent of the initial Si/Ni ratio in the precursor.",

author = "Xinghua Liu and Chun, {C. M.} and Aksay, {Ilhan A.} and Shih, {Wei Heng}",

year = "2000",

doi = "10.1021/ie990129l",

language = "English (US)",

volume = "39",

pages = "684--692",

journal = "Industrial and Engineering Chemistry Research",

issn = "0888-5885",

publisher = "American Chemical Society",

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T1 - Synthesis of mesostructured nickel oxide with silica

AU - Liu, Xinghua

AU - Chun, C. M.

AU - Aksay, Ilhan A.

AU - Shih, Wei Heng

PY - 2000

Y1 - 2000

N2 - Mesostructured nickel oxide was formed with nickel sulfate and cationic surfactant cetyltrim-ethylammonium bromide (CTAB). X-ray diffraction (XRD) peaks at low scattering angles and transmission electron microscopy (TEM) indicated that a mesostructure was formed. However, these XRD patterns disappeared after calcination. The addition of sodium silicate in the precursor solutions produced a mesostructure, which is stable against calcination. Surface areas as high as 530 m2/g can be obtained for the nickel silicate mesophase. TEM-EDXS showed that the Si/Ni molar ratio in the mesophase is ~0.5, independent of the initial Si/Ni ratio in the precursor.

AB - Mesostructured nickel oxide was formed with nickel sulfate and cationic surfactant cetyltrim-ethylammonium bromide (CTAB). X-ray diffraction (XRD) peaks at low scattering angles and transmission electron microscopy (TEM) indicated that a mesostructure was formed. However, these XRD patterns disappeared after calcination. The addition of sodium silicate in the precursor solutions produced a mesostructure, which is stable against calcination. Surface areas as high as 530 m2/g can be obtained for the nickel silicate mesophase. TEM-EDXS showed that the Si/Ni molar ratio in the mesophase is ~0.5, independent of the initial Si/Ni ratio in the precursor.

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DO - 10.1021/ie990129l

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EP - 692

JO - Industrial and Engineering Chemistry Research

JF - Industrial and Engineering Chemistry Research

IS - 3

ER -

Synthesis of mesostructured nickel oxide with silica

Abstract

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