Synthesis of (+)-Lineariifolianone and Related Cyclopropenone-Containing Sesquiterpenoids

Keyphrases

• Natural Products 100%
• Cyclopropenone 100%
• Sesquiterpenoids 100%
• Overall Yield 50%
• Protonation 50%
• Synthetic Routes 50%
• Epoxide Ring Opening 50%
• Enolates 50%
• Absolute Configuration 50%
• Stereoconvergent 50%
• Stereocenters 50%
• Diols 50%
• Eight-step 50%
• (+)-Valencene 50%
• Eremophilane 50%

Chemistry

• Cyclopropenone 100%
• Sesquiterpenoid 100%
• Natural Product 100%
• Enolates 50%
• Absolute Configuration 50%
• Eremophilane 50%
• Kinetics of Protonation 50%
• (+)-Valencene 50%
• Enantiomer 50%
• Epoxide 50%
• Diol 50%