Synthesis of bis(imino)pyridine iron amide and ammonia compounds from an N-H transfer agent

Amanda C. Bowman, Suzanne C. Bart, Frank W. Heinemann, Karsten Meyer, Paul J. Chirik

Research output: Contribution to journalArticle

24 Scopus citations

Abstract

Addition of the [NH] transfer reagent Hdbabh (dbabh = 2,3:5,6-dibenzo-7- azabicyelo[2.2.1]hepta-2,5-diene) to the bis(imino)pyr-idine iron bis(dinitrogen) complex, ( lPrPDI)Fe(N 2) 2 ( PrPDI = 2,6-(2,6 -1Pr 2C 6H 3N=CMe) 2C 5H 3N), furnished the corresponding iron amide and ammonia compounds, resulting from cleavage of the strained amine. Isotopic labeling studies support N-H bond activation by a transient, parent imide, [( iprPDI)FeNH].

Original languageEnglish (US)
Pages (from-to)5587-5589
Number of pages3
JournalInorganic Chemistry
Volume48
Issue number13
DOIs
StatePublished - Jul 6 2009
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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