Synthesis of bis(imino)pyridine iron amide and ammonia compounds from an N-H transfer agent

Amanda C. Bowman; Suzanne C. Bart; Frank W. Heinemann; Karsten Meyer; Paul J. Chirik

doi:10.1021/ic9003017

Synthesis of bis(imino)pyridine iron amide and ammonia compounds from an N-H transfer agent

Amanda C. Bowman, Suzanne C. Bart, Frank W. Heinemann, Karsten Meyer, Paul J. Chirik

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

Addition of the [NH] transfer reagent Hdbabh (dbabh = 2,3:5,6-dibenzo-7- azabicyelo[2.2.1]hepta-2,5-diene) to the bis(imino)pyr-idine iron bis(dinitrogen) complex, ( ^lPrPDI)Fe(N ₂) ₂ ( ^PrPDI = 2,6-(2,6 ^-1Pr ₂C ₆H ₃N=CMe) ₂C ₅H ₃N), furnished the corresponding iron amide and ammonia compounds, resulting from cleavage of the strained amine. Isotopic labeling studies support N-H bond activation by a transient, parent imide, [( ^iprPDI)FeNH].

Original language	English (US)
Pages (from-to)	5587-5589
Number of pages	3
Journal	Inorganic Chemistry
Volume	48
Issue number	13
DOIs	https://doi.org/10.1021/ic9003017
State	Published - Jul 6 2009
Externally published	Yes

All Science Journal Classification (ASJC) codes

Inorganic Chemistry
Physical and Theoretical Chemistry

Access to Document

10.1021/ic9003017

Cite this

@article{8795e21c16f944c7b7fdb86809671c8d,

title = "Synthesis of bis(imino)pyridine iron amide and ammonia compounds from an N-H transfer agent",

abstract = "Addition of the [NH] transfer reagent Hdbabh (dbabh = 2,3:5,6-dibenzo-7- azabicyelo[2.2.1]hepta-2,5-diene) to the bis(imino)pyr-idine iron bis(dinitrogen) complex, ( lPrPDI)Fe(N 2) 2 ( PrPDI = 2,6-(2,6 -1Pr 2C 6H 3N=CMe) 2C 5H 3N), furnished the corresponding iron amide and ammonia compounds, resulting from cleavage of the strained amine. Isotopic labeling studies support N-H bond activation by a transient, parent imide, [( iprPDI)FeNH].",

author = "Bowman, {Amanda C.} and Bart, {Suzanne C.} and Heinemann, {Frank W.} and Karsten Meyer and Chirik, {Paul J.}",

year = "2009",

month = jul,

day = "6",

doi = "10.1021/ic9003017",

language = "English (US)",

volume = "48",

pages = "5587--5589",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "13",

}

TY - JOUR

T1 - Synthesis of bis(imino)pyridine iron amide and ammonia compounds from an N-H transfer agent

AU - Bowman, Amanda C.

AU - Bart, Suzanne C.

AU - Heinemann, Frank W.

AU - Meyer, Karsten

AU - Chirik, Paul J.

PY - 2009/7/6

Y1 - 2009/7/6

N2 - Addition of the [NH] transfer reagent Hdbabh (dbabh = 2,3:5,6-dibenzo-7- azabicyelo[2.2.1]hepta-2,5-diene) to the bis(imino)pyr-idine iron bis(dinitrogen) complex, ( lPrPDI)Fe(N 2) 2 ( PrPDI = 2,6-(2,6 -1Pr 2C 6H 3N=CMe) 2C 5H 3N), furnished the corresponding iron amide and ammonia compounds, resulting from cleavage of the strained amine. Isotopic labeling studies support N-H bond activation by a transient, parent imide, [( iprPDI)FeNH].

AB - Addition of the [NH] transfer reagent Hdbabh (dbabh = 2,3:5,6-dibenzo-7- azabicyelo[2.2.1]hepta-2,5-diene) to the bis(imino)pyr-idine iron bis(dinitrogen) complex, ( lPrPDI)Fe(N 2) 2 ( PrPDI = 2,6-(2,6 -1Pr 2C 6H 3N=CMe) 2C 5H 3N), furnished the corresponding iron amide and ammonia compounds, resulting from cleavage of the strained amine. Isotopic labeling studies support N-H bond activation by a transient, parent imide, [( iprPDI)FeNH].

UR - http://www.scopus.com/inward/record.url?scp=67649867850&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=67649867850&partnerID=8YFLogxK

U2 - 10.1021/ic9003017

DO - 10.1021/ic9003017

M3 - Article

C2 - 19361163

AN - SCOPUS:67649867850

SN - 0020-1669

VL - 48

SP - 5587

EP - 5589

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 13

ER -

Synthesis of bis(imino)pyridine iron amide and ammonia compounds from an N-H transfer agent

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this