Synthesis of an end-capped sexithiophene bearing fused tetrathiafulvalene (TTF) units

Alexander L. Kanibolotsky; Lyudmila Kanibolotskaya; Sergey Gordeyev; Peter J. Skabara; Iain McCulloch; Rory Berridge; Jan E. Lohr; Filippo Marchioni; Fred Wudl

doi:10.1021/ol070366h

Synthesis of an end-capped sexithiophene bearing fused tetrathiafulvalene (TTF) units

Alexander L. Kanibolotsky
, Lyudmila Kanibolotskaya
, Sergey Gordeyev
, Peter J. Skabara
, Iain McCulloch
, Rory Berridge
, Jan E. Lohr
, Filippo Marchioni
, Fred Wudl

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

Equation presented We report the synthesis of a novel end-capped sexithiophene derivative bearing two pendent, fused tetrathiafulvalene (TTF) units linked to the main chain through 1,4-dithiin heterocycles. Cyclic voltammetry and absorption spectroscopy are used to investigate the electronic properties of this hybrid electroactive material. The oligomer has a band gap of 2.1 eV, and the material can be oxidized through the sexithiophene and TTF units simultaneously.

Original language	English (US)
Pages (from-to)	1601-1604
Number of pages	4
Journal	Organic letters
Volume	9
Issue number	8
DOIs	https://doi.org/10.1021/ol070366h
State	Published - Apr 12 2007
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

Access to Document

10.1021/ol070366h

Cite this

@article{94ca0d40695d45eea9cd109c62a4fc38,

title = "Synthesis of an end-capped sexithiophene bearing fused tetrathiafulvalene (TTF) units",

abstract = "Equation presented We report the synthesis of a novel end-capped sexithiophene derivative bearing two pendent, fused tetrathiafulvalene (TTF) units linked to the main chain through 1,4-dithiin heterocycles. Cyclic voltammetry and absorption spectroscopy are used to investigate the electronic properties of this hybrid electroactive material. The oligomer has a band gap of 2.1 eV, and the material can be oxidized through the sexithiophene and TTF units simultaneously.",

author = "Kanibolotsky, \{Alexander L.\} and Lyudmila Kanibolotskaya and Sergey Gordeyev and Skabara, \{Peter J.\} and Iain McCulloch and Rory Berridge and Lohr, \{Jan E.\} and Filippo Marchioni and Fred Wudl",

year = "2007",

month = apr,

day = "12",

doi = "10.1021/ol070366h",

language = "English (US)",

volume = "9",

pages = "1601--1604",

journal = "Organic letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "8",

}

TY - JOUR

T1 - Synthesis of an end-capped sexithiophene bearing fused tetrathiafulvalene (TTF) units

AU - Kanibolotsky, Alexander L.

AU - Kanibolotskaya, Lyudmila

AU - Gordeyev, Sergey

AU - Skabara, Peter J.

AU - McCulloch, Iain

AU - Berridge, Rory

AU - Lohr, Jan E.

AU - Marchioni, Filippo

AU - Wudl, Fred

PY - 2007/4/12

Y1 - 2007/4/12

N2 - Equation presented We report the synthesis of a novel end-capped sexithiophene derivative bearing two pendent, fused tetrathiafulvalene (TTF) units linked to the main chain through 1,4-dithiin heterocycles. Cyclic voltammetry and absorption spectroscopy are used to investigate the electronic properties of this hybrid electroactive material. The oligomer has a band gap of 2.1 eV, and the material can be oxidized through the sexithiophene and TTF units simultaneously.

AB - Equation presented We report the synthesis of a novel end-capped sexithiophene derivative bearing two pendent, fused tetrathiafulvalene (TTF) units linked to the main chain through 1,4-dithiin heterocycles. Cyclic voltammetry and absorption spectroscopy are used to investigate the electronic properties of this hybrid electroactive material. The oligomer has a band gap of 2.1 eV, and the material can be oxidized through the sexithiophene and TTF units simultaneously.

UR - https://www.scopus.com/pages/publications/34247517363

UR - https://www.scopus.com/pages/publications/34247517363#tab=citedBy

U2 - 10.1021/ol070366h

DO - 10.1021/ol070366h

M3 - Article

C2 - 17381099

AN - SCOPUS:34247517363

SN - 1523-7060

VL - 9

SP - 1601

EP - 1604

JO - Organic letters

JF - Organic letters

IS - 8

ER -

Synthesis of an end-capped sexithiophene bearing fused tetrathiafulvalene (TTF) units

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this